超高效合相色谱法快速检测塑料食品接触材料中13种紫外吸收剂

doi:10.3724/SP.J.1123.2019.03026

色谱 ›› 2019, Vol. 37 ›› Issue (9): 990-995.DOI: 10.3724/SP.J.1123.2019.03026

超高效合相色谱法快速检测塑料食品接触材料中13种紫外吸收剂

邱月^1,2, 李根容¹, 龙梅¹, 李沿飞¹, 夏之宁²

1. 重庆市计量质量检测研究院, 重庆 401123;
2. 重庆大学化学化工学院, 重庆 400030

收稿日期:2018-03-21 出版日期:2019-09-08 发布日期:2015-07-30
通讯作者: 邱月
基金资助:
重庆市科研院所绩效激励引导专项（cstc2018jxj10007）.

Rapid determination of 13 ultraviolet absorbents in plastic food contact materials by ultra-performance convergence chromatography

QIU Yue^1,2, LI Genrong¹, LONG Mei¹, LI Yanfei¹, XIA Zhining²

1. Chongqing Academy of Metrology and Quality Inspection, Chongqing 401123, China;
2. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, China

Received:2018-03-21 Online:2019-09-08 Published:2015-07-30
Supported by:
Chongqing Scientific Research Institute Performance Incentive and Guidance Special Project (No.cstc2018jxj100007).

摘要/Abstract

摘要： 建立了一种同时检测塑料食品接触材料中13种紫外吸收剂的超高效合相色谱法。以甲醇为溶剂对塑料食品接触材料样品进行超声提取，经C18固相萃取柱净化，过0.22 μm有机滤膜，采用超高效合相色谱仪分析。选择ACQUTY UPC² HSS C18 SB色谱柱（150 mm×3.0 mm，1.8 μm），以超临界二氧化碳为流动相，异丙醇为改性剂进行梯度洗脱，在最优色谱条件下，13种紫外吸收剂能够在4 min内实现有效分离。结果表明，在各自线性范围内，13种紫外吸收剂的线性关系良好，标准曲线相关系数不低于0.9985，检出限（S/N=3）为0.05~0.15 mg/kg，加标回收率为86.8%~115.7%，相对标准偏差为0.73%~5.61%。该方法快速简便，准确可靠，同时大大减少了有机溶剂的消耗，可用于塑料食品接触材料中13种紫外吸收剂的快速检测。

关键词: 超高效合相色谱, 超声提取, 塑料食品接触材料, 紫外吸收剂

Abstract: A rapid method based on ultra-performance convergence chromatography (UPC²) was developed for the analysis of 13 ultraviolet (UV) absorbents in plastic food contact materials. The UV absorbents were extracted from plastic food contact materials by supersonic extraction with methanol, purified by C18 solid phase extraction column, and analyzed via UPC² before filtration with an organic filtration membrane (0.22 μm). An ACQUTY UPC² HSS C18 SB chromatographic column (150 mm×3.0 mm, 1.8 μm) was used for the detection of the UV absorbents. An effective separation was achieved within 4 min under the optimized conditions. The mobile phases were supercritical carbon dioxide and isopropanol as a modifier. The results showed that the 13 UV absorbents exhibited good linear relationships in the respective linear ranges with the correlation coefficients no less than 0.9985. The limits of detection (S/N=3) were in the range of 0.05-0.15 mg/kg. The recoveries were from 86.8% to 115.7%, and the relative standard deviations were between 0.73% and 5.61%. This method is rapid, convenient, accurate and reliable, and can be used for the rapid determination of the 13 UV absorbents in plastic food contact materials.

Key words: plastic food contact materials, ultra-performance convergence chromatography (UPC²), ultrasonic extraction, ultraviolet absorbents

中图分类号:

O658

邱月, 李根容, 龙梅, 李沿飞, 夏之宁. 超高效合相色谱法快速检测塑料食品接触材料中13种紫外吸收剂[J]. 色谱, 2019, 37(9): 990-995.

QIU Yue, LI Genrong, LONG Mei, LI Yanfei, XIA Zhining. Rapid determination of 13 ultraviolet absorbents in plastic food contact materials by ultra-performance convergence chromatography[J]. Chinese Journal of Chromatography, 2019, 37(9): 990-995.

参考文献

[1] Derya B, Abidin B, Tobias S, et al. Synthetic Met, 2012, 162(23):2047

[2] Kemei P, Zhihua C, Weiguo C. J Mol Struct, 2013, 1032(30):100
[3] Guo Z Y, Wang H M, Ding Z M. Gansu Petroleum and Chemical Industry, 2007, 3:14 郭振宇, 王红梅, 丁著明. 甘肃石油和化工, 2007, 3:14
[4] Joon-Woo K, Tomohiko I, Babu R R. Chemosphere, 2011, 85:751

[5] Fent K, Chew G, Li J, et al. Sci Total Environ, 2014, 482/483:125
[6] Ou W H, Tang C M, Wang C W, et al. Chinese Journal of Analytical Chemistry, 2015, 43(5):734 欧玮辉, 唐才明, 王春维, 等. 分析化学, 2015, 43(5):734
[7] Lin R, Lai Y, Lin W J, et al. Journal of Analytical Testing, 2015, 34(1):20 林睿, 赖莺, 林伟靖, 等. 分析测试学报, 2015, 34(1):20
[8] Wang X M, Wang J, Du T T, et al. Chinese Journal of Chromatography, 2018, 36(3):190 王雪梅, 王娟, 杜彤彤, 等. 色谱, 2018, 36(3):190
[9] Negreira N, Rodríguez I, Ramil M. Anal Chim Acta, 2009, 654(2):162

[10] Peng X Z, Jin J B, Wang C W. J Chromatogr A, 2015, 1384:97

[11] Carpinteiro I, Abuín B, Rodríguez I. J Chromatogr A, 2010, 1217:3729

[12] Liu Y S, Ying G G, Shareef A, et al. J Chromatogr A, 2011, 1218:5328

[13] Gou X L, Huang W W, Zhao X Y, et al. Analytical Instrument, 2017, 5:31 勾新磊, 黄雯雯, 赵新颖, 等. 分析仪器, 2017, 5:31
[14] Yan Y, Zhu-Ge H T, Wen C, et al. Journal of Food Safety and Quality Inspection, 2018, 2:434 晏嫣, 诸葛海涛, 闻诚, 等. 食品安全质量检测学报, 2018, 2:434
[15] Zhang Q, Liu Y, Gu H, et al. Chinese Journal of Analysis Laboratory, 2017, 36(3):357 张强, 刘艳, 顾华, 等. 分析试验室, 2017, 36(3):357
[16] Li C F, Li Y, Chen Z N, et al. Chinese Journal of Chromatography, 2014, 32(6):616 李成发, 李英, 陈枝楠, 等. 色谱, 2014, 32(6):616

[17] Zhang Y, Du Z X, Yu W L. Chinese Journal of Chromatography, 2014, 32(1):52 张云, 杜振霞, 于文莲. 色谱, 2014, 32(1):52

[18] Zhou Q, Gao B, Zhang X, et al. Food Chem, 2014, 143:199

[19] Gong X, Qi N, Wang X, et al. Food Chem, 2014, 162:172

[20] Wang L T, Wang B, Zhou W, et al. Chinese Journal of Analytical Chemistry, 2015, 43(7):1047 王丽婷, 王波, 周围, 等. 分析化学, 2015, 43(7):1047
[21] Fan Y L, Ma M, Cui H Z, et al. J Sep Sci, 2018, 41:2993

[22] Li W L, Li X M, Li G R, et al. Chinese Journal of Chromatography, 2016, 34(8):795 李武林, 李雪敏, 李根容, 等. 色谱, 2016, 34(8):795

[23] Gee P T, Liew C Y, Thong M C, et al. Food Chem, 2016, 196:367

[24] Zhang X F, Yang J L, Chen J, et al. Chinese Journal of Chromatography, 2018, 36(5):417 张弦飞, 杨军丽, 陈娟, 等. 色谱, 2018, 36(5):417
[25] Zhang L X, Sun J Y, Wang Y H, et al. Chinese Journal of Chromatography, 2018, 36(6):566 章璐幸, 孙洁胤, 王延辉, 等. 色谱, 2018, 36(6):566
[26] Kaori T, Eiichiro F, Takeshi B. J Chromatogr A, 2013, 1299:103

超高效合相色谱法快速检测塑料食品接触材料中13种紫外吸收剂

Rapid determination of 13 ultraviolet absorbents in plastic food contact materials by ultra-performance convergence chromatography

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	蔡美贞. 超声提取-气相色谱-质谱法测定本草香中16种颗粒态多环芳烃含量及其排放特征分析[J]. 色谱, 2022, 40(12): 1111-1118.
[2]	李佳晨, 曹玲, 方方, 施海蔚, 黄青, 谭力, 段巧莲, 冯有龙. 超高效合相色谱法快速测定保健食品中10种脂溶性维生素[J]. 色谱, 2022, 40(12): 1136-1142.
[3]	丁友超, 曹丽华, 周丽萍, 钱凯, 汤娟, 周佳, 董绍伟. 超声提取-高温燃烧吸收-离子色谱法测定纺织品中可吸附有机卤化物[J]. 色谱, 2022, 40(1): 74-81.
[4]	张科明, 邓鸣, 苏媛媛, 谢东, 许有诚, 刘向红. 超高效液相色谱-二极管阵列检测法同时测定化妆品中22种防晒剂[J]. 色谱, 2021, 39(4): 415-423.
[5]	张文华, 洪灯, 雷美康, 胡晓莉, 侯建波, 谢文, 徐敦明, 伊雄海, 李优. 超高效合相色谱法拆分和测定克伦特罗对映体[J]. 色谱, 2021, 39(12): 1347-1354.
[6]	杨光勇, 郭苍亭, 薛光, 郭金喜. 超高效合相色谱-串联质谱法测定食用植物油和油条中15种3-氯-1,2-丙二醇脂肪酸酯[J]. 色谱, 2020, 38(12): 1388-1395.
[7]	张文华, 谢文, 侯建波, 陈钦可, 李淑敏, 祝泽龙, 邹学权, 徐敦明. 超高效合相色谱法对6种三唑类农药对映体的拆分及其在黄瓜中的残留分析[J]. 色谱, 2019, 37(12): 1356-1362.
[8]	张弦飞, 杨军丽, 陈娟, 师彦平. 超高效合相色谱-串联质谱法快速测定枸杞中甜菜碱含量(英文)[J]. 色谱, 2018, 36(5): 417-424.
[9]	王雪梅, 王娟, 杜彤彤, 马晓敏, 卢小泉. 基于石墨烯海绵的固相萃取-液相色谱法测定化妆品中6种紫外吸收剂[J]. 色谱, 2018, 36(3): 190-194.
[10]	王成云, 李成发, 林君峰, 谢堂堂, 褚乃清. 超高效液相色谱/静电场轨道阱高分辨质谱法同时测定塑料食品接触材料中光稳定剂和抗氧化剂的特定迁移量[J]. 色谱, 2017, 35(5): 509-519.
[11]	李武林, 李雪敏, 李根容, 李沿飞, 徐溢, 李泽全. 超高效合相色谱快速检测塑料制品中的15种邻苯二甲酸酯[J]. 色谱, 2016, 34(8): 795-800.
[12]	勾新磊, 赵新颖, 池海涛, 高峡, 周明强, 刘伟丽. 固相萃取-超高效液相色谱-串联质谱法同时测定食品接触塑料制品中10种苯并三唑类紫外吸收剂[J]. 色谱, 2015, 33(6): 571-576.
[13]	林春花, 谢贤清, 范乃立, 涂媛鸿, 陈彦, 廖维林. 超高效合相色谱-质谱法快速分析食用植物油中常见脂肪酸[J]. 色谱, 2015, 33(4): 397-402.
[14]	戴雪伟, 卫碧文, 望秀丽, 于文佳, 徐永威. 超高效合相色谱快速分析塑料制品中的18种多环芳烃[J]. 色谱, 2015, 33(10): 1059-1064.
[15]	李成发, 李英, 陈枝楠, 梁烽, 陈旭辉, 吴绍精, 李泳涛, 孙小颖. 高效液相色谱法同时测定食品接触材料中抗氧化剂和紫外吸收剂的迁移量[J]. 色谱, 2014, 32(6): 616-622.