金属有机框架材料的研究进展

doi:10.3724/SP.J.1123.2013.10002

色谱 ›› 2014, Vol. 32 ›› Issue (2): 107-116.DOI: 10.3724/SP.J.1123.2013.10002

金属有机框架材料的研究进展

翟睿^1,2, 焦丰龙², 林虹君², 郝斐然², 李佳斌², 颜辉², 李楠楠², 王欢欢², 金祖耀², 张养军², 钱小红²

1. 北京工业大学生命科学与生物工程学院, 北京 100022;
2. 蛋白质组学国家重点实验室, 北京蛋白质组研究中心, 军事医学科学院放射与辐射医学研究所, 北京 102206

收稿日期:2013-10-08 修回日期:2013-11-22 出版日期:2014-02-08 发布日期:2014-01-25
通讯作者: 钱小红，张养军
基金资助:
国家重大科学计划项目(2012CB910603，2010CB912704)；国家重大科学仪器设备开发专项项目(2011YQ030139，2011YQ06008408，2011YQ09000504，2012YQ12004407)；国家高技术研究发展计划项目(2012AA020202)；国家自然科学基金重点项目(20735005，21275159，31100591).

Progress in metal-organic frameworks

ZHAI Rui^1,2, JIAO Fenglong², LIN Hongjun², HAO Feiran², LI Jiabin², YAN Hui², LI Nannan², WANG Huanhuan², JIN Zuyao², ZHANG Yangjun², QIAN Xiaohong²

1. College of Life Science and Bio-Engineering, Beijing University of Technology, Beijing 100022, China;
2. State Key Laboratory of Proteomics, Beijing Proteome Research Center, Beijing Institute of Radiation Medicine, Beijing 102206, China

Received:2013-10-08 Revised:2013-11-22 Online:2014-02-08 Published:2014-01-25

摘要/Abstract

摘要：

金属有机框架(metal-organic frameworks，MOFs)材料是一类由有机配体与金属中心经过自组装形成的具有可调节孔径的材料。与传统无机多孔材料相比，MOFs材料具有更大的比表面积，更高的孔隙率，结构及功能更加多样，因而已经被广泛应用于气体吸附与分离、传感器、药物缓释、催化反应等领域中。新兴材料的出现极大地促进了各个学科间的相互发展，本文综述了近年来MOFs材料的研究发展，包括MOFs材料自身的特点、国内外发展现状、应用领域以及复合MOFs材料的研究热点，并对今后的发展进行了展望。

关键词: 多孔材料, 金属有机框架, 配位聚合物

Abstract:

Metal-organic frameworks (MOFs) are a class of crystalline materials built from organic binding ligands and metal ions through self-assembly. Currently, MOFs have drawn a growing interest among the scientific teams of various fields. Compared with conventional inorganic porous materials, MOFs possess larger specific surface areas, higher porosity and diversity of structures and functions, thus many potential applications have been proposed in the domains of gas adsorption and separation, sensors, drug delivery, catalysis or others. The combinations of MOFs and other materials such as graphene oxide, magnetic nanoparticles have obvious advantages in adsorption and separation. The appearance of novel materials greatly promotes interdisciplinary developments such as organic chemistry, inorganic chemistry, coordination chemistry, materials chemistry, life science and computer science. This article reviews the progress of MOFs in recent years, including the characteristics of MOFs, advances at home and abroad, applications, central issues of compound MOFs and the prospects in the future.

Key words: coordination polymers, metal-organic frameworks (MOFs), porous materials

中图分类号:

O658

翟睿, 焦丰龙, 林虹君, 郝斐然, 李佳斌, 颜辉, 李楠楠, 王欢欢, 金祖耀, 张养军, 钱小红. 金属有机框架材料的研究进展[J]. 色谱, 2014, 32(2): 107-116.

ZHAI Rui, JIAO Fenglong, LIN Hongjun, HAO Feiran, LI Jiabin, YAN Hui, LI Nannan, WANG Huanhuan, JIN Zuyao, ZHANG Yangjun, QIAN Xiaohong. Progress in metal-organic frameworks[J]. Chinese Journal of Chromatography, 2014, 32(2): 107-116.

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金属有机框架材料的研究进展

Progress in metal-organic frameworks

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