Ion-pair chromatography-indirect ultraviolet detection for determination of tetraethyl ammonium using a monolithic column and a packed column

doi:10.3724/SP.J.1123.2015.03043

Abstract

Abstract:

Two methods were developed for the determination of tetraethyl ammonium by ion-pair chromatography-indirect ultraviolet detection using a monolithic column and a packed column with ionic liquid as additive in mobile phase. Chromatographic separations were performed on a monolithic column and a packed column both on reversed phase using imidazolium ionic liquid aqueous solution-ion-pair reagent-organic solvent as mobile phase. The effects of the background ultraviolet absorption reagent, detection wavelength, ion-pair reagent, organic solvent, column temperature and flow rate on the determination of tetraethyl ammonium were investigated. The difference between the two chromatographic columns was compared and the retention rules were discussed. Under the optimized chromatographic conditions, for tetraethyl ammonium on monolithic column and packed column, the retention times were 2.40 and 3.02 min; the detection limits (S/N=3), 0.04 and 0.07 mg/L; the RSDs (n=5) for peak areas, 0.16% and 0.11%; and the RSDs (n=5) for retention times, 0.02% and 0.01%, respectively. The two methods have been successfully applied to the determination of tetraethyl ammonium ionic liquids synthesized by laboratory. The recoveries of the tetraethyl ammonium after spiking were 98.2% and 99.1%, respectively. The two methods can meet the requirements for the quantitative analysis of tetraethyl ammonium.

Key words: imidazolium ionic liquids, indirect ultraviolet detection, ion-pair chromatography, monolithic column, packed column, tetraethyl ammonium

CLC Number:

O658

ZOU Chunmiao, ZHANG Xiaodong, YU Hong, GUAN Chao, WANG Miaoyu. Ion-pair chromatography-indirect ultraviolet detection for determination of tetraethyl ammonium using a monolithic column and a packed column[J]. Chinese Journal of Chromatography, 2015, 33(7): 759-764.

References

[1] Chen H Q, Li G F, He G Y, et al. Fine Chemicals (陈海群, 李根发, 何光裕, 等. 精细化工), 2009, 26(9): 870

[2] Zhao B, Chen D J, Li Y L, et al. Journal of Molecular Catalysis (赵彬, 陈殿军, 李永路, 等. 分子催化), 2008, 22(6): 487

[3] Li X X. Journal of Shanxi Agricultural University: Natural Science Edition (李晓旭. 山西农业大学学报: 自然科学版), 2007, 27(1): 99

[4] Jia L L, Zhang W F. Chinese Journal of Disinfection (贾丽丽, 张文福. 中国消毒学杂志), 2008, 25(1): 64

[5] Lin X Y, Hu H P, Liu H. Journal of Changsha University of Electric Power (林向阳, 胡慧萍, 刘辉. 长沙电力学院学报), 2004, 19(3): 91

[6] Zhuang H R. Environmental Monitoring in China (庄会荣. 中国环境监测), 2004, 20(5): 25

[7] Li M R, Sun F L, Guo C H, et al. China Surfactant Detergent & Cosmetics (李美蓉, 孙方龙, 郭长会, 等. 日用化学工业), 2012, 42(5): 383

[8] Liu J Q, Zhai Z L, Zhang X B, et al. Chinese Journal of Disinfection (刘吉起, 翟志雷, 张向兵, 等. 中国消毒学杂志), 2012, 29(1): 51

[9] Jin Y, Chen Z F. Chemical World (金燕, 陈志峰. 化学世界), 1999(5): 266

[10] Lu S, Ji R. Industrial Water Treatment (卢姝, 纪然. 工业水处理), 2011, 31(9): 76

[11] Yu X H, Hao L H, Liu K Y, et al. Chinese Journal of Veterinary Drug (于晓辉, 郝利华, 柳焜耀, 等. 中国兽药杂志), 2012, 46(2): 33

[12] He S M, Liu Y Q, Han S T, et al. Chinese Journal of Spectroscopy Laboratory (何书美, 刘彦钦, 韩士田, 等. 光谱实验室), 2000, 17(1): 61

[13] Liu Z J, Chen W D, Zhu F Y, et al. Journal of Analytical Science (刘壮峻, 陈卫东, 朱凤英, 等. 分析科学学报), 2006, 22(3): 312

[14] Gao X X, Qi J, Zhao M X, et al. Spectroscopy and Spectral Analysis (高秀香, 齐剑, 赵梅仙, 等. 光谱学与光谱分析), 2008, 28(6): 1420

[15] Bai L G, Niu W J, Yang G L. Chinese Journal of Chromatography (白立改, 牛文敬, 杨更亮. 色谱), 2013, 31(4): 303

[16] Liu Y C, Liu Z. Chinese Journal of Chromatography (刘云春, 刘震. 色谱), 2013, 31(4): 348

[17] Li J, Zhu Y. Chinese Journal of Analytical Chemistry (李晶, 朱岩. 分析化学), 2013, 41(3): 400

[18] Ma Y J, Li M, Yu H, et al. Chinese Chemical Letters, 2013, 24(12): 1067

[19] Dou A B, Zou C J, Shan Y H, et al. Chinese Journal of Chromatography (窦阿波, 邹存杰, 单圆鸿, 等. 色谱), 2014, 32(5): 447

[20] Kuang Y Y, Wang Y, Gu X, et al. Chinese Journal of Chromatography (况媛媛, 王彦, 谷雪, 等. 色谱), 2014, 32(4): 388

[21] Liu H Y, Ding W H. J Chromatogr A, 2004, 1025(2): 303

[22] Zhou X J, Shi Y P. Chinese Journal of Chromatography (周贤婧, 师彦平. 色谱), 2013, 31(7): 661

[23] Sun Y M, Yu H. Chinese Journal of Chromatography (孙艺梦, 于泓. 色谱), 2013, 31(10): 969

[24] An Y, Yu H, Zou C M. Chinese Journal of Analytical Chemistry (安莹, 于泓, 邹春苗. 分析化学), 2013, 41(7): 1057

[25] Zheng X R, Ma Y J, Yu H. Journal of Instrumental Analysis (郑秀荣, 马亚杰, 于泓. 分析测试学报), 2014, 33(9): 1026

[26] Wang M Y, Yu H, Li P, et al. Chinese Journal of Chromatography (王淼煜, 于泓, 李萍, 等. 色谱), 2014, 32(7): 773

[27] Ruiz-Angel M J, Berthod A. J Chromatogr A, 2006, 1113 (1/2): 101

[28] Yang L L, Zhang X Z, Tian H F. Chinese Journal of Inorganic Analytical Chemistry (杨兰玲, 张习志, 田海峰. 中国无机分析化学), 2012, 28(2): 43