Simultaneous determination of 12 direct dyes in cosmetics by high performance liquid chromatography

doi:10.3724/SP.J.1123.2018.04014

Abstract

Abstract:

A method was developed for the simultaneous separation and determination of 12 direct dyes in cosmetics by high performance liquid chromatography (HPLC). The analytes were separated on an XB-C₁₈ column with acetonitrile-0.02 mol/L ammonium acetate aqueous solution (pH 9.0) as the mobile phases, and were detected using a diode array detector. The results indicated that the 12 direct dyes had good linearities with correlation coefficients greater than 0.999. The limits of detection were between 0.017 μ g/g and 1.7 μ g/g. The average recoveries ranged from 85.6% to 113.4%, and the relative standard deviations (RSDs) ranged from 1.0% to 7.7%. The intra-and inter-day RSDs were 0.4%-6.5% and 0.2%-7.5%, respectively. The method is simple, rapid, accurate, and is suitable for the determination of direct dyes in cosmetics.

Key words: cosmetics, direct dyes, high performance liquid chromatography (HPLC)

CLC Number:

O658

PAN Cheng, WU Ling, XIE Yong, XU Wenqi, BAI Yang, HUANG Yonghui, HU Chaoyang. Simultaneous determination of 12 direct dyes in cosmetics by high performance liquid chromatography[J]. Chinese Journal of Chromatography, 2018, 36(9): 904-910.

References

[1] Ren G J, Sun Z J, Wang L Z, et al. Flavour Fragrance Cosmetics, 2017(1):42 任国杰, 孙稚菁, 王灵芝, 等. 香料香精化妆品, 2017(1):42
[2] Robens J F, Dill G S, Ward J M, et al. J Toxicol Appl Pharmacol, 1980, 54(3):431
[3] Zhou X, Tang Y. Dyestuffs and Coloration, 2018, 55(1):11 周鑫, 唐勇. 染料与染色, 2018, 55(1):11
[4] Fathi M R, Asfaram A, Farhangi A. Spectrochim Acta A, 2015, 135:364
[5] Cheng Z J, Zhang L, Guo X, et al. Spectrochim Acta A, 2015, 137:1126
[6] Kallel F, Bouaziz F, Chaari F, et al. Process Saf Environ, 2016, 102:30
[7] Zhang C, Zhang W H, Yu M X, et al. J Porous Mater, 2017, 24(5):1289
[8] Arica T A, Ayas E, Arica M Y, et al. Micropor Mesopor Mat, 2017, 243:164
[9] Fard Z M, Bagheri M, Rabieh S, et al. J Mater Sci-Mater Electron, 2017, 28(13):9618
[10] Salem M A, Bakr E A, Elattar H G. Spectrochim Acta A, 2018, 188:155
[11] Mir A A, Amooey A A, Ghasemi S, et al. J Clean Prod, 2018, 170:570
[12] Walger E, Marlin N, Molton F, et al. Molecules, 2018, 23(2):242
[13] Naseem K, Farooqi Z H, Begum R, et al. J Clean Prod, 2018, 187:296
[14] Deng L, Si Z, Peng X X, et al. Journal of Safety and Environment, 2017, 17(2):677 邓林, 施周, 彭晓旭, 等. 安全与环境学报, 2017, 17(2):677
[15] Ma R H, Zhou G H. Textile Auxiliaries, 2018, 35(3):21 马荣华, 周光红. 印染助剂, 2018, 35(3):21
[16] EC No. 1223/2009
[17] China Food and Drug Administration. Safety and Technical Standards for Cosmetics (2015 Edition). (2015-12-23)[2018-08-15]. http://samr.cfda.gov.cn/directory/web/WS01/images/MjAxNcTqtdoyNji6xbmruOa4vbz+LnBkZg==.pdf 国家食品药品监督管理总局. 化妆品安全技术规范(2015版). (2015-12-23)[2018-08-15]. http://samr.cfda.gov.cn/directory/web/WS01/images/MjAxNcTqtdoyNji6xb mruOa4vbz+LnBkZg==.pdf
[18] Jiang D M, Huang M Y, Fang R M, et al. Chinese Journal of Analysis Laboratory, 2017, 36(3):264 蒋德敏, 黄美英, 方荣美, 等. 分析试验室, 2017, 36(3):264
[19] Fang R Q. Fujian Analysis and Testing, 2017, 26(6):1 方荣谦. 福建分析测试, 2017, 26(6):1
[20] Shi F. Fujian Analysis and Testing, 2010, 19(2):60 侍芳. 福建分析测试, 2010, 19(2):60
[21] Ding Y C, Cao X Z, Wu L N, et al. Chinese Journal of Chromatography, 2008, 26(5):603 丁友超, 曹锡忠, 吴丽娜, 等. 色谱, 2008, 26(5):603
[22] He F P, Shi F, Pan L T. Environmental Pollution and Control, 2011, 33(4):71 贺锋萍, 侍芳, 潘碌亭. 环境污染与防治, 2011, 33(4):71
[23] Lü G, Feng Z J, Cao L J, et al. Physical Testing and Chemical Analysis (Part B:Chemical Analysis), 2011, 47(11):1310 吕刚, 冯智劼, 曹丽静, 等. 理化检验:化学分册, 2011, 47(11):1310
[24] Ling R, Hu W Y, Qiao L. Journal of Instrumental Analysis, 2012, 31(6):730 凌睿, 胡文彦, 乔玲. 分析测试学报, 2012, 31(6):730
[25] Lin H, Xu C X, Yan C R, et al. Chinese Journal of Chromatography, 2013, 31(9):914 林慧, 徐春祥, 颜春荣, 等. 色谱, 2013, 31(9):914
[26] Xiu X L, Luo X, Niu Z Y, et al. Chinese Journal of Chromatography, 2013, 31(10):961 修晓丽, 罗忻, 牛增元, 等. 色谱, 2013, 31(10):961
[27] Gou Y, Geng Z, Zhang Y F, et al. Chinese Journal of Pharmaceutical Analysis, 2017, 37(3):461 苟琰, 耿昭, 张燕飞, 等. 药物分析杂志, 2017, 37(3):461
[28] Lin H, Xu C X, Liu C Z, et al. Journal of Food Safety and Quality, 2017, 8(4):1389 林慧, 徐春祥, 刘成志, 等. 食品安全质量检测学报, 2017, 8(4):1389
[29] Luo L, Dong T, Ma L K. Journal of Chinese Medicinal Materials, 2017, 40(11):2546 罗镭, 董婷, 马临科. 中药材, 2017, 40(11):2546
[30] Li L, Liu J, Wang F. Chinese Journal of Analytical Chemistry, 2016, 44(7):1112 李兰, 刘俊, 王丰. 分析化学, 2016, 44(7):1112
[31] Lü S, Ji H, Pu A J, et al. Dyestuffs and Coloration, 2016, 53(2):54 吕双, 季浩, 蒲爱军, 等. 染料与染色, 2016, 53(2):54
[32] Chen L, Wen J X, Lei Y, et al. Journal of Instrumental Analysis, 2015, 34(9):1008 陈林, 温家欣, 雷毅, 等. 分析测试学报, 2015, 34(9):1008
[33] Dou C Y, Ma Y S, Kang Z S, et al. Journal of Food Safety and Quality, 2015, 6(2):563 窦彩云, 马育松, 康占省, 等. 食品安全质量检测学报, 2015, 6(2):563
[34] Zhong C P, Wei W, Wang Z H, et al. Journal of Food Science, 2014, 35(10):195 钟慈平, 魏炜, 王正虹, 等. 食品科学, 2014, 35(10):195
[35] GB/T 20382-2006