Chinese Journal of Chromatography ›› 2021, Vol. 39 ›› Issue (4): 368-375.DOI: 10.3724/SP.J.1123.2020.05038
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LIAO Yingmin1,*(), HUANG Xiaojia2,*(), WANG Zhuozhuo2, GAN Rui1
Received:
2020-05-30
Online:
2021-04-08
Published:
2021-03-08
Contact:
LIAO Yingmin,HUANG Xiaojia
Supported by:
CLC Number:
LIAO Yingmin, HUANG Xiaojia, WANG Zhuozhuo, GAN Rui. Research progress in the application of magnetic solid phase extraction based on carbon based magnetic materials in food analysis[J]. Chinese Journal of Chromatography, 2021, 39(4): 368-375.
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URL: https://www.chrom-china.com/EN/10.3724/SP.J.1123.2020.05038
Carbon base | Carbon based magnetic composite material | Analyte | Samples | Method | LOD | Recovery/ % | RSD/ % | Ref. | |
---|---|---|---|---|---|---|---|---|---|
CNTs | Fe3O4/AMWNTs | pyrethroid pesticides | honey | GC | 0.07-0.20 μg/L | 78.4 | -94.8 | 3.8-8.1 | [ |
MWCNT-Fe3O4 | phthalate acid esters | yogurt-based drinking | GC-MS | 10.00-24.00 ng/L | - | 0.3-7.4 | [ | ||
MWCNT-MNP | polycyclic aromatic hydrocarbons | milk, milk powder | GC-MS | 0.040-0.075 μg/kg | 86.1 | -100.3 | 3.2-10.1 | [ | |
Tol-MCNT | sulfonamides | milk | LC-HRMS | 2.00-10.00 ng/L | 86.6 | -98.3 | 0.9-6.2 | [ | |
M-N-CNTs | bisphenols | fruit juices | UHPLC-MS/MS | 0.43-2.47 ng/L | 90.6 | -101.0 | 1.2-5.8 | [ | |
PAMAM@Mag-CNTs | toxic alkaloids | meat, vegetable | UFLC-MS/MS | 0.011-0.329 ng/g | 83.4 | -125.0 | 1.3-8.0 | [ | |
PEG-MWCNTs-MNP | mycotoxins | real liquid milk | UHPLC-Q-Exactive HRMS | 0.005-0.050 μg/kg | 81.8 | -106.4 | 2.1-8.5 | [ | |
HCSs@Fe3O4- MWCNT-COOH | herbicides | wheat flour | HPLC-DAD | 0.24-0.68 ng/g | 88.8 | -96.6 | 1.6-6.2 | [ | |
Fe3O4/MWCNT@ND | vitamin B12 | infant formula powder, cereal | HPLC-DAD | 2.85 ng/mL | 97.8 | -103.1 | 4.3-6.1 | [ | |
N-CNTCs | okadaic acid | mussel, oyster | HPLC-MS/MS | 1.30 pg/mL | 82.0 | -107.0 | 1.8-2.5 | [ | |
mMWCNT-ZrO2-C18 | polycyclic aromatic hydrocarbons | edible oils | HPLC-DAD | 0.06-0.55 ng/g | 93.9 | -113.3 | 3.9-6.0 | [ | |
G | Fe3O4@SiO2@G | preservative | vegetables | GC-MS | 0.21-11.50 μg/kg | 78.3 | -116.7 | 1.4-11.9 | [ |
MG@SiO2-TMSPED | pesticides | tomato, grape | GC-μECD | 0.23-0.30 μg/kg | 82.0 | -113.0 | 5.1-8.1 | [ | |
mNi@N-GrT | tetracyclines | milk | HPLC | 1.29-2.31 ng/mL | 91.6 | -109.7 | 2.2-5.7 | [ | |
3D-G-Fe3O4 | caffeine | food | GC-FID | 0.10 μg/mL | 93.1 | -97.7 | 5.9-7.1 | [ | |
3D-G-Fe3O4 | organophosphorus pesticides | juice | GC-NPD | 1.20-5.10 ng/L | 86.6 | -107.5 | 2.5-7.4 | [ | |
3D-G-Fe3O4 | chlorophenols | honey | HPLC-UV | 1.00-1.50 ng/g | 93.2 | -98.9 | 4.1-4.6 | [ | |
GO | Fe3O4@GO | sulfonamides | milk | HPLC-MS/MS | 0.02-0.13 μg/L | 73.4 | -97.4 | 1.0-8.2 | [ |
Fe3O4@SiO2-GO/ MIL-101(Cr) | triazine herbicides | rice | HPLC | 0.01-0.08 μg/kg | 83.9 | -103.5 | 0.5-8.7 | [ | |
MGO | phthalate esters | bottled water | HPLC | 0.004-0.013 mg/L | 65.0 | -126.0 | 0.6-6.0 | [ | |
Fe3O4/GO | melamine | dairy products | HPLC | 0.03 μg/L | 97.2 | -103.1 | 1.1-5.0 | [ | |
Fe3O4/rGO | aflatoxins | vegetable oils | HPLC-PCD-FLD | 0.01-0.02 μg/kg | 80.4 | -106.0 | 1.3-10.5 | [ | |
rGO/ZnFe2O4 | estrogens | fish | HPLC-DAD | 0.01-0.02 ng/mL | 73.5 | -104.1 | 1.7-8.3 | [ | |
MOFs | MNPCs | organophosphorus pesticides | fruit | GC-FPD | 0.018-0.045 μg/L | 84.0 | -116.0 | 3.5-9.7 | [ |
AC | MBAC | phenylurea herbicides | juice | HPLC-UV | 0.10-0.80 ng/mL | 86.1 | -104.1 | 4.0-6.8 | [ |
BC | C/Fe3O4 NCs | triazole fungicides | fruit | GC-MS | 0.12-0.55 μg/kg | 82.1 | -109.9 | 2.1-8.4 | [ |
GC | YS-Fe3O4@GC | sulfonamides | milk, meat | HPLC | 0.11-0.25 μg/L | 77.2 | -118.0 | 1.4-9.2 | [ |
Table 1 Application of magnetic solid phase extraction (MSPE) based on carbon based magnetic materials in food analysis
Carbon base | Carbon based magnetic composite material | Analyte | Samples | Method | LOD | Recovery/ % | RSD/ % | Ref. | |
---|---|---|---|---|---|---|---|---|---|
CNTs | Fe3O4/AMWNTs | pyrethroid pesticides | honey | GC | 0.07-0.20 μg/L | 78.4 | -94.8 | 3.8-8.1 | [ |
MWCNT-Fe3O4 | phthalate acid esters | yogurt-based drinking | GC-MS | 10.00-24.00 ng/L | - | 0.3-7.4 | [ | ||
MWCNT-MNP | polycyclic aromatic hydrocarbons | milk, milk powder | GC-MS | 0.040-0.075 μg/kg | 86.1 | -100.3 | 3.2-10.1 | [ | |
Tol-MCNT | sulfonamides | milk | LC-HRMS | 2.00-10.00 ng/L | 86.6 | -98.3 | 0.9-6.2 | [ | |
M-N-CNTs | bisphenols | fruit juices | UHPLC-MS/MS | 0.43-2.47 ng/L | 90.6 | -101.0 | 1.2-5.8 | [ | |
PAMAM@Mag-CNTs | toxic alkaloids | meat, vegetable | UFLC-MS/MS | 0.011-0.329 ng/g | 83.4 | -125.0 | 1.3-8.0 | [ | |
PEG-MWCNTs-MNP | mycotoxins | real liquid milk | UHPLC-Q-Exactive HRMS | 0.005-0.050 μg/kg | 81.8 | -106.4 | 2.1-8.5 | [ | |
HCSs@Fe3O4- MWCNT-COOH | herbicides | wheat flour | HPLC-DAD | 0.24-0.68 ng/g | 88.8 | -96.6 | 1.6-6.2 | [ | |
Fe3O4/MWCNT@ND | vitamin B12 | infant formula powder, cereal | HPLC-DAD | 2.85 ng/mL | 97.8 | -103.1 | 4.3-6.1 | [ | |
N-CNTCs | okadaic acid | mussel, oyster | HPLC-MS/MS | 1.30 pg/mL | 82.0 | -107.0 | 1.8-2.5 | [ | |
mMWCNT-ZrO2-C18 | polycyclic aromatic hydrocarbons | edible oils | HPLC-DAD | 0.06-0.55 ng/g | 93.9 | -113.3 | 3.9-6.0 | [ | |
G | Fe3O4@SiO2@G | preservative | vegetables | GC-MS | 0.21-11.50 μg/kg | 78.3 | -116.7 | 1.4-11.9 | [ |
MG@SiO2-TMSPED | pesticides | tomato, grape | GC-μECD | 0.23-0.30 μg/kg | 82.0 | -113.0 | 5.1-8.1 | [ | |
mNi@N-GrT | tetracyclines | milk | HPLC | 1.29-2.31 ng/mL | 91.6 | -109.7 | 2.2-5.7 | [ | |
3D-G-Fe3O4 | caffeine | food | GC-FID | 0.10 μg/mL | 93.1 | -97.7 | 5.9-7.1 | [ | |
3D-G-Fe3O4 | organophosphorus pesticides | juice | GC-NPD | 1.20-5.10 ng/L | 86.6 | -107.5 | 2.5-7.4 | [ | |
3D-G-Fe3O4 | chlorophenols | honey | HPLC-UV | 1.00-1.50 ng/g | 93.2 | -98.9 | 4.1-4.6 | [ | |
GO | Fe3O4@GO | sulfonamides | milk | HPLC-MS/MS | 0.02-0.13 μg/L | 73.4 | -97.4 | 1.0-8.2 | [ |
Fe3O4@SiO2-GO/ MIL-101(Cr) | triazine herbicides | rice | HPLC | 0.01-0.08 μg/kg | 83.9 | -103.5 | 0.5-8.7 | [ | |
MGO | phthalate esters | bottled water | HPLC | 0.004-0.013 mg/L | 65.0 | -126.0 | 0.6-6.0 | [ | |
Fe3O4/GO | melamine | dairy products | HPLC | 0.03 μg/L | 97.2 | -103.1 | 1.1-5.0 | [ | |
Fe3O4/rGO | aflatoxins | vegetable oils | HPLC-PCD-FLD | 0.01-0.02 μg/kg | 80.4 | -106.0 | 1.3-10.5 | [ | |
rGO/ZnFe2O4 | estrogens | fish | HPLC-DAD | 0.01-0.02 ng/mL | 73.5 | -104.1 | 1.7-8.3 | [ | |
MOFs | MNPCs | organophosphorus pesticides | fruit | GC-FPD | 0.018-0.045 μg/L | 84.0 | -116.0 | 3.5-9.7 | [ |
AC | MBAC | phenylurea herbicides | juice | HPLC-UV | 0.10-0.80 ng/mL | 86.1 | -104.1 | 4.0-6.8 | [ |
BC | C/Fe3O4 NCs | triazole fungicides | fruit | GC-MS | 0.12-0.55 μg/kg | 82.1 | -109.9 | 2.1-8.4 | [ |
GC | YS-Fe3O4@GC | sulfonamides | milk, meat | HPLC | 0.11-0.25 μg/L | 77.2 | -118.0 | 1.4-9.2 | [ |
Fig. 1 Illustration of the procedure for synthesis of C/Fe3O4 NCs and MSPE steps for triazole fungicides analysis in fruits[35] C/Fe3O4 NCs: carbon-based Fe3O4 nanocomposites.
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