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色谱

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复杂基体中痕量多环芳烃分析测定方法的研究进展

董新艳,杨亦文,任其龙

  

  1. National Laboratory of Secondary Resources Chemical Engineering, Zhejiang University, Hangzhou 310027, China
  • 收稿日期:2004-11-18 修回日期:1900-01-01 出版日期:2005-11-30 发布日期:1987-12-25
  • 通讯作者: 杨亦文

Progress in the Determination of Trace Polycyclic Aromatic Hydrocarbons in Complex Matrices

DONG Xinyan, YANG Yiwen, REN Qilong   

  1. National Laboratory of Secondary Resources Chemical Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:2004-11-18 Revised:1900-01-01 Online:2005-11-30 Published:1987-12-25

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摘要：

介绍了环境样品（水和土壤）以及植物油中痕量多环芳烃的分析检测方法。对样品的预处理过程和分析方法做了评价。采用一些新的预处理方法（包括液相色谱法、固相萃取法、超临界二氧化碳萃取法）,并结合色谱-质谱在线联用分析检测方法能够获得比较理想的分析结果。引用文献52篇。

关键词: 多环芳烃, 高效液相色谱, 痕量分析, 气相色谱 , 水, 土壤, 植物油

Abstract:

The analytical methods of polycyclic aromatic hydrocarbons （PAHs) in different samples, e.g., vegetable oils, waters and soils, have been reviewed. The sample pretreatment steps play a key role during the analysis due to the very low PAHs contents. The pretreatment methods for water samples include liquid-liquid extraction, solid phase extraction, etc. The pretreatment methods for soil samples include Soxhlet extraction, ultrasonic extraction, microwave assisted extraction, accelerated solvent extraction, and supercritical fluid extraction, etc. The pretreatment methods for vegetable oils include saponification, liquid-liquid partitioning, caffeine complexation, solid phase extraction, and supercritical fluid extraction, etc. Gas chromatography with mass spectrometry and high performance liquid chromatography (HPLC) with fluorescence detection are mainly used for separation and detection. The novel on-line determination method, e.g., the coupling of liquid chromatography with high performance liquid chromatography, or with gas chromatography may obtain ideal results. Fifty-two references are cited.

Key words: gas chromatography , high performance liquid chromatography, soils, trace analysis, vegetable oils, waters, polycyclic aromatic hydrocarbons