全二维气相色谱在石油地质样品分析中的应用进展

doi:10.3724/SP.J.1123.2014.07010

摘要/Abstract

摘要：

对石油地质样品的化学组成进行全面准确的剖析，可以获得丰富的地球化学信息，为油气勘探工作提供科学依据。然而，该类样品除了组成复杂之外，还易受到各种物理（如蒸发、乳化、扩散、溶解和吸附）、化学（如光降解）和生物（如微生物降解）过程的影响。这些特点给样品的分析研究工作带来了极大的困难，传统的一维气相色谱/质谱技术很难对其进行理想的分离。全二维气相色谱（GC×GC）作为新发展起来的一种分离技术，在复杂样品分析方面具有独特的优势，虽然在石油地质样品分析中的应用相对较晚，但也日益受到关注。本文主要综述了近5年来GC×GC在石油地质方面国内外的研究进展以及存在的主要问题，并对今后的研究进行了展望。

关键词: 全二维气相色谱, 生物标志物, 烃源岩, 原油

Abstract:

Abundant geochemical information can be acquired by analyzing the chemical compositions of petroleum geological samples. The information obtained from the analysis provides scientifical evidences for petroleum exploration. However, these samples are complicated and can be easily influenced by physical (e. g. evaporation, emulsification, natural dispersion, dissolution and sorption), chemical (photodegradation) and biological (mainly microbial degradation) weathering processes. Therefore, it is very difficult to analyze the petroleum geological samples and they cannot be effectively separated by traditional gas chromatography/mass spectrometry. A newly developed separation technique, comprehensive two-dimensional gas chromatography (GC×GC), has unique advantages in complex sample analysis, and recently it has been applied to petroleum geological samples. This article mainly reviews the research progresses in the last five years, the main problems and the future research about GC×GC applied in the area of petroleum geology.

Key words: biomarkers, comprehensive two-dimensional gas chromatography (GC×GC), crude oil, source rock

中图分类号:

O658

高儇博, 常振阳, 代威, 童婷, 张万峰, 何生, 朱书奎. 全二维气相色谱在石油地质样品分析中的应用进展[J]. 色谱, 2014, 32(10): 1058-1065.

GAO Xuanbo, CHANG Zhenyang, DAI Wei, TONG Ting, ZHANG Wanfeng, HE Sheng, ZHU Shukui. Recent advances in analysis of petroleum geological samples by comprehensive two-dimensional gas chromatography[J]. Chinese Journal of Chromatography, 2014, 32(10): 1058-1065.

参考文献

[1] Peters K E, Walters C C, Moldowan J M. The Biomarker Guide: Biomarkers and Isotopes in Petroleum Exploration and Earth History. Cambridge, UK: Cambridge University Press, 2005
[2] Ventura G T, Hall G J, Nelson R K, et al. J Chromatogr A, 2011, 1218: 2584
[3] Aguiar A, Silva A I, Azevedo D A, et al. Fuel, 2010, 89: 2760
[4] Springer M V, Garcia D F, Goncalves F T T, et al. Org Geochem, 2010, 41: 1013
[5] Eiserbeck C, Nelson R K, Grice K, et al. Geochim Cosmochim Acta, 2012, 87: 299
[6] Pasumarthi R, Chandrasekaran S, Mutnuri S. Mar Pollut Bull, 2013, 76(1/2): 276
[7] Ahmed M, George S C. Org Geochem, 2004, 35: 137
[8] Cheng D, Wang L J, Shahbazi A, et al. Fuel, 2014, 130: 251
[9] Chen W T, Zhang Y H, Zhang J X, et al. Appl Energ, 2014, 128: 209
[10] Greenwood P F, Summons R E. Org Geochem, 2003, 34: 1211
[11] Pieri N, Jacquot F, Mille G, et al. Org Geochem, 1996, 25: 51
[12] Zhang S C, Huang H P, Su J, et al. Org Geochem, 2014, 67: 41
[13] Munoz D, Doumenq P, Guiliano M, et al. Talanta, 1997, 45(1): 1
[14] Xiu S N, Shahbazi A, Shirley V B, et al. Bioresource Technol, 2011, 102(2): 1928
[15] Escobar M, Márquez G, Inciarte S, et al. Org Geochem, 2011, 42: 727
[16] Soares R F, Pereira R, Silva R S F, et al. J Brazil Chem Soc, 2013
[17] Dutriez T, Thiébaut D, Courtiade M, et al. Fuel, 2013, 104: 583
[18] Nizio K D, Harynuk J J. J Chromatogr A, 2012, 1252: 171
[19] Harvey P M, Shellie R A. Anal Chem, 2012, 84(15): 6501
[20] Zhu S K, Lu X, Xing J, et al. Anal Chim Acta, 2005, 545(2): 224
[21] Zheng Y M, Feng F, Guo W, et al. Chinese Journal of Chromatography (郑月明, 冯峰, 国伟, 等. 色谱), 2012, 30(11): 1166
[22] Wu J F, Lu X, Tang W Y, et al. J Chromatogr A, 2004, 1034: 199
[23] Lu X, Zhao M Y, Kong H W, et al. J Chromatogr A, 2004, 1043: 265
[24] Guo K, Zhou J, Liu Z L. Chinese Journal of Chromatography (郭琨, 周建, 刘泽龙. 色谱), 2012, 30(2): 128
[25] Xu G W, Ye F, Kong H W, et al. Chinese Journal of Chromatography (许国旺, 叶芬, 孔宏伟, 等. 色谱), 2001, 19(2): 132
[26] Beens J, Tijssena R, Blombergb J. J Chromatogr A, 1998, 822: 233
[27] Murray J A. J Chromatogr A, 2012, 1261: 58
[28] Blomberg J, Brinkman U A T, Schoenmakers P J. J Chromatogr A, 2002, 972: 137
[29] Wang H T, Weng N, Zhang S C, et al. Science China: Earth Science (王汇彤, 翁娜, 张水昌, 等. 中国科学: 地球科学), 2011, 41(11): 1586
[30] Wang H T, Weng N, Zhang S C, et al. Chinese Science Bulletin (王汇彤, 翁娜, 张水昌, 等. 科学通报), 2010, 55(21): 2129
[31] Jiang Q G, Ma Y Y, Qian M H, et al. Petroleum Geology and Experiment (蒋启贵, 马媛媛, 钱门辉, 等. 石油实验地质), 2012, 34(3): 303
[32] Ruan C H, Ye F, Kong H W, et al. Chinese Journal of Analytical Chemistry (阮春海, 叶芬, 孔宏伟, 等. 分析化学), 2002, 30(5): 548
[33] Mango F D. Geochim Cosmochim Acta, 1990, 54: 1315
[34] Mango F D. Geochim Cosmochim Acta, 1990, 54: 23
[35] Mango F D. Geochim Cosmochim Acta, 1992, 56: 553
[36] Mango F D. Geochim Cosmochim Acta, 1994, 58: 895
[37] Wang P R, Zhu J Z, Fang X L. Acta Petrolei Sinica (王培荣, 朱俊章, 方孝林. 石油学报), 1998, 1(19): 24
[38] Zhang C M, Jin D W. Oil & Gas Geology (张春明, 金迪威. 石油与天然气地质), 1997, 18 (4): 332
[39] Zhang M, Zhang J. Facult-Block Oil & Gas Field (张敏, 张俊. 断块油气田), 2000, 7(1): 14
[40] Qian Z H, Yin C. Petroleum Geology and Experiment (钱志浩, 寅曹. 石油实验地质), 2001, 23(2): 186
[41] Cai X Y, Zhu Y M. Petroleum Geology and Experiment (蔡勋育, 朱扬明. 石油实验地质), 2006, 28(4): 380
[42] Peters K E, Moldowan J M. The Biomarker Guide: Interpreting Molecular Fossils in Petroleum and Ancient Sediments: Englewood Cliffs. New Jersey: Prentice Hall, 1993
[43] Obermajer M, Osadetz K G, Fowler M G, et al. Org Geochem, 2000, 31: 959
[44] Wang P R, Zhao H, Xiao T R, et al. Progress in Natural Science (王培荣, 赵红, 肖廷荣, 等. 自然科学进展), 2007, 17(8): 1144
[45] Grice K, Alexander R, Kagi R I. Org Geochem, 2000, 31: 67
[46] Wang G L, Shi S B, Wang P R, et al. Fuel, 2013, 107: 706
[47] Eiserbeck C, Nelson R K, Grice K, et al. Geochim Cosmochim Acta, 2012, 87: 299
[48] Li S F, Hu S Z, Cao J, et al. Int J Mol Sci, 2012, 13(12): 11399
[49] Silva R C, Silva R S F, de Castro E V R, et al. Fuel, 2013, 112: 125
[50] Jiang Q G, Wang Q, Ma Y Y, et al. Petroleum Geology and Experiment (蒋启贵, 王强, 马媛媛, 等. 石油实验地质), 2009, 31(6): 627
[51] Zhu G Y, Wang H T, Weng N, et al. Org Geochem, 2013, 63: 8
[52] Wang H T, Zhang S C, Weng N, et al. Petroleum Exploration and Development (王汇彤, 张水昌, 翁娜, 等. 石油勘探与开发), 2012, 39(1): 132
[53] Wang H T, Zhang S C, Weng N, et al. Petroleum Exploration and Development (王汇彤, 张水昌, 翁娜, 等. 石油勘探与开发), 2012, 39(1): 123
[54] Wang P R, Xu G J, Xiao T R, et al. China Offshore Oil and Gas (王培荣, 徐冠军, 肖廷荣, 等. 中国海上油气), 2009, 21(5): 296
[55] Payeur A L, Meyers P A, Sacks R D. Org Geochem, 2011, 42: 1263
[56] Wang F C, Walters C C. Anal Chem, 2007, 79(15): 5642
[57] Zhu S K, Tong T, Zhang W F, et al. Sci World J, 2014, 2014: 1
[58] von Mühlen C, Zini C A, Caramao E B, et al. J Chromatogr A, 2006, 1105: 39
[59] Frysinger G S, Gaines R B. J Sep Sci, 2001, 24(2): 87
[60] Aguiar A, Aguiar H G M, Azevedo D A, et al. Energ Fuel, 2011, 25(3): 1060
[61] Juyal P, McKenna A M, Yen A, et al. Energ Fuel, 2011, 25(1): 172
[62] Oliveira C R, Ferreira A A, Oliveira C J F, et al. Org Geochem, 2012, 46: 154
[63] Kiepper A P, Casilli A, Azevedo D A. Org Geochem, 2014, 70: 62
[64] Silva R S F, Aguiar H G M, Rangel M D, et al. Fuel, 2011, 90(8): 2694
[65] Casilli A, Silva R C, Laakia J, et al. Org Geochem, 2014, 68: 61
[66] Eiserbeck C, Nelson R K, Grice K, et al. J Chromatogr A, 2011, 1218: 5549
[67] Olivares M, Irazola M, Vallejo A, et al. J Chromatogr A, 2011, 1218: 1656
[68] Lu H, Shi Q, Lu J, et al. Energ Fuel, 2013, 27(12): 7245
[69] Wang H T, Weng N, Zhang S C, et al. Sci China: Earth Sci, 2011, 54(12): 1892
[70] Wang H T, Weng N, Zhang S C, et al. Journal of Chinese Mass Spectrometry Society (王汇彤, 翁娜, 张水昌, 等. 质谱学报), 2010, 31(1): 18
[71] Li S F, Hu S Z, He S, et al. Geological Science and Technology Information (李水福, 胡守志, 何生, 等. 地质科技情报), 2010, 29(5): 46
[72] Mullins O C, Ventura G T, Nelson R K, et al. Energ Fuel, 2008, 22(1): 496
[73] Pomerantz A E, Ventura G T, McKenna A M, et al. Org Geochem, 2010, 41: 812
[74] Ventura G T, Raghuraman B, Nelson R K, et al. Org Geochem, 2010, 41: 1026
[75] Oliveira C R, Oliveira C J F, Ferreira A A, et al. Org Geochem, 2012, 53: 131
[76] Wang H T, Weng N, Zhang S C, et al. Chinese Sci Bull, 2010, 55(19): 2039
[77] Wang G L, Li N X, Gao B, et al. Chinese Sci Bull, 2013, 58(28/29): 3588
[78] Zhu S K, Zhang W F, Dai W, et al. Anal Methods, 2014, 6(8): 2608
[79] Wingert W S. Fuel, 1992, 71: 37
[80] Chen J H, Fu J M, Sheng G Y, et al. Org Geochem, 1996, 25: 179
[81] Lin R, Wilk Z A. Fuel, 1995, 74: 1512
[82] Dahl J E, Moldowan J M, Peters K E, et al. Nature, 1999, 399: 54
[83] Li J, Philip P R, Cui M. Org Geochem, 2000, 31: 267
[84] Azevedo D A, Tamanqueira J B, Dias J C M, et al. Fuel, 2008, 87: 2122
[85] Jalees M I, Bianchi T S, Sassen R, et al. Evaporite, 2011, 26: 155
[86] Li S F, Hu S Z, Cao J, et al. Petroleum Geology and Experiment (李水福, 胡守志, 曹剑, 等. 石油实验地质), 2011, 33(6): 645
[87] Wei Z B, Mankiewicz P, Walters C, et al. Org Geochem, 2011, 42: 121
[88] Frysinger G S, Gaines R B, Xu L, et al. Environ Sci Technol, 2003, 37: 1653
[89] Simoneit B R T, Lein A Y, Peresypkin V I, et al. Geochim Cosmochim Acta, 2004, 68: 2275
[90] Sutton P A, Lewis C A, Rowland S J. Org Geochem, 2005, 36: 963
[91] Gough M A, Rowland S J. Nature, 1990, 334: 648
[92] Gough M A, Rhead M M, Rowland S J. Org Geochem, 1992, 18: 17
[93] Ventura G T, Kenig F, Reddy C M, et al. Org Geochem, 2008, 39: 846
[94] Tran T C, Logan G A, Grosjean E, et al. Geochim Cosmochim Acta, 2010, 74(22): 6468
[95] Zhang J H, Feng Z H, Fang W, et al. Sci China: Earth Sci, 2014, 57(2): 297

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