多接收器电感耦合等离子体质谱方法的开发和应用进展

doi:10.3724/SP.J.1123.2020.07030

色谱 ›› 2021, Vol. 39 ›› Issue (1): 4-9.DOI: 10.3724/SP.J.1123.2020.07030

多接收器电感耦合等离子体质谱方法的开发和应用进展

张璐瑶¹^,², 陈子谷¹^,², 杨学志¹^,², 陆达伟¹, 刘倩¹^,²^,^*(), 江桂斌¹^,²

1.中国科学院生态环境研究中心, 环境化学与生态毒理学国家重点实验室, 北京 100085
2.中国科学院大学资源与环境学院, 北京 100190

收稿日期:2020-07-27 出版日期:2021-01-08 发布日期:2020-12-20
通讯作者: 刘倩
作者简介:刘倩: 中国科学院生态环境研究中心研究员、博士生导师,环境化学与生态毒理学国家重点实验室副主任,中国科学院大学资环学院岗位教授,中国化学会有机分析专业委员会、青年化学工作者委员会委员,中国环境科学学会环境化学分会秘书长。国家杰出青年基金、优秀青年基金获得者。主要研究方向为环境分析化学、环境污染与健康,在环境污染物超痕量分析及溯源方面做出了较为系统的工作。已在Nat Nanotechnol, Nat Commun, Angew Chem Int Ed, Environ Sci Technol等期刊发表SCI论文100余篇。获科学探索奖、国家自然科学二等奖、CAIA奖特等奖、MIT TR35 China、中国化学会青年化学奖、全国优博等奖励。*Tel:(010)62849124,E-mail:qianliu@rcees.ac.cn.
基金资助:
国家自然科学基金项目(21825403);国家自然科学基金项目(21976194);国家自然科学基金项目(21904134)

Recent advances in method development and application of multi-collector inductively coupled plasma mass spectrometry

ZHANG Luyao¹^,², CHEN Zigu¹^,², YANG Xuezhi¹^,², LU Dawei¹, LIU Qian¹^,²^,^*(), JIANG Guibin¹^,²

1. State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
2. College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100190, China

Received:2020-07-27 Online:2021-01-08 Published:2020-12-20
Contact: LIU Qian
Supported by:
National Natural Science Foundation of China(21825403);National Natural Science Foundation of China(21976194);National Natural Science Foundation of China.(21904134)

摘要/Abstract

摘要：

稳定同位素分析是分析化学一项颇具前景的分支,通过精确测定物质的稳定同位素比值,可以追溯物质来源并探究其转化过程。高精度稳定同位素分析技术的进步依赖于新一代质谱仪的不断发展。其中,多接收器电感耦合等离子体质谱(MC-ICP-MS)是近年发展迅速的一种同位素组成测定工具。稳定同位素分析对样品基质十分敏感,复杂基质能严重干扰同位素测定的精密度和准确度。这对MC-ICP-MS的样品净化提出了极高要求,目前也是同位素分析领域的热点问题。该文聚焦于近年来MC-ICP-MS在样品净化及仪器联用方法方面的相关研究进展,并展望了MC-ICP-MS稳定同位素分析的应用前景。

关键词: 多接收器电感耦合等离子体质谱, 离子交换色谱, 同位素分析, 样品净化, 联用技术

Abstract:

Stable isotopic analysis is an important branch of analytical chemistry. Accurate determination of the stable isotopic compositions of substances is critical for tracing their sources and investigating their transformation processes. The new generation of mass spectrometry technology has greatly facilitated the development of high-precision stable isotopic analysis methods. In particular, multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) has emerged as a powerful tool for isotopic composition determination. However, isotopic analysis by MC-ICP-MS is highly sensitive to the sample matrix, which may compromise the precision and accuracy of the analysis. Therefore, it is particularly important to reduce the sample matrix effect using efficient sample purification techniques. This article summarizes the recent progress in sample purification and instrument hyphenation methods for MC-ICP-MS, and provides perspectives on the future application of MC-ICP-MS in different fields.

Key words: multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS), ion-exchange chromatography (IEC), isotopic analysis, sample purification, hyphenated technology

中图分类号:

O658

张璐瑶, 陈子谷, 杨学志, 陆达伟, 刘倩, 江桂斌. 多接收器电感耦合等离子体质谱方法的开发和应用进展[J]. 色谱, 2021, 39(1): 4-9.

ZHANG Luyao, CHEN Zigu, YANG Xuezhi, LU Dawei, LIU Qian, JIANG Guibin. Recent advances in method development and application of multi-collector inductively coupled plasma mass spectrometry[J]. Chinese Journal of Chromatography, 2021, 39(1): 4-9.

图/表 1

参考文献

[1]	Lu D, Zhang T, Yang X, et al. J Anal At Spectrom, 2017,32(10):1848
[2]	Tian L, Gong Y, Wei W, et al. J Anal At Spectrom, 2020,35(8):1566
[3]	Feng L, Zhou L, Hu W, et al. J Anal At Spectrom, 2020,35(1):145
[4]	Fan J, Li J, Wang Q, et al. Chem Geol, 2020,545:119648
[5]	Tan D, Zhu J, Wang X, et al. J Anal At Spectrom, 2020,35(4):713
[6]	Li X, Han G, Zhang Q, et al. J Anal At Spectrom, 2020,35(7):1330
[7]	Mahan B M, Wu F, Dosseto A, et al. J Anal At Spectrom, 2020,35(5):863
[8]	Creech B J, Schaefer F B, Turner P S. Geostand Geoanal Res, 2020,44(2):223
[9]	Dellinger M, Hilton R G, Nowell G M. J Anal At Spectrom, 2020,35(2):377
[10]	Gonzalez de Vega C, Costas-Rodriguez M, Van Acker T, et al. Anal Chem, 2020,92(5):3572
[11]	Zhang C, Zhao H, Zhang W, et al. J Anal At Spectrom, 2020,35(9):1887
[12]	Desaulty A M, Lach P, Perret S. J Anal At Spectrom, 2020,35(8):1537
[13]	Thermo Scientific^TM. Low-level Lead Speciation and Isotope Ratio Analysis by GC-MC-ICP-MS. [2020-07-04]. https://www.thermofisher.com/cn/zh/home.html
[14]	Karasiński J, Nguyen-Marcińczyk C T, Wojciechowski M, et al. J Anal At Spectrom, 2020,35(3):560
[15]	Lu D, Liu Q, Zhang T, et al. Nat Nanotechnol, 2016,11(8):682
[16]	Yang X, Liu X, Zhang A, et al. Nat Commun, 2019,10(1):1620
[17]	Lu D, Liu Q, Yu M, et al. Environ Sci Technol, 2018,52(3):1088
[18]	Lu D, Tan J, Yang X, et al. Atmos Chem Phys, 2019,19(5):2861
[19]	Yang X, Lu D, Tan J, et al. Environ Sci Technol, 2020,54(12):7126
[20]	Lu D, Luo Q, Chen R, et al. Nat Commun, 2020,11(1):2567
[21]	Forsyth J E, Weaver K L, Maher K, et al. Environ Sci Technol, 2019,53(19):11429
[22]	Miller K A, Vicentini F A, Hirota S A, et al. Proc Natl Acad Sci U S A, 2019,116(13):5955
[23]	Bourgon N, Jaouen K, Bacon A M, et al. Proc Natl Acad Sci U S A, 2020,117(9):4675
[24]	Martin J E, Tacail T, Braga J, et al. Nat Commun, 2020,11(1):3587
[25]	Oleinikova O V, Poitrasson F, Drozdova O Y, et al. Environ Sci Technol, 2019,53(19):11183

Isotopes	Separation media		Standard material		Sample matrix		Instrumentation		Reference
¹⁰⁰Mo,⁹⁸Mo, ⁹⁷Mo,⁹⁵Mo	TRU Spec resin		NIST SRM 3134, BCR-2, BHVO-2, AGV-2, W-2, SGR-1, NOD-P-1, NOD-A-1		rock reference materials, seawater		MC-ICP-MS		[3]
¹⁰⁰Mo,⁹⁸Mo, ⁹⁷Mo,⁹⁵Mo	AG1-X8 (100-200 mesh), BPAH resin		NIST SRM 3134, BCR-2		igneous rock		MC-ICP-MS		[4]
¹¹⁴Cd,¹¹³Cd, ¹¹¹Cd,¹¹⁰Cd	AGMP-1M (100-200 mesh)		NIST 3108, BAM-I012, Spex-Cd		rock reference materials		MC-ICP-MS		[5]
⁴¹K,³⁹K	AG50W-X12 (200-400 mesh)		NIST SRM 3141a, GBW (E) 081590, BCR-2, BHVO-2, AGV-2, JG-2, GSP-2, DNC-1a, RGM-2, SDC-1, W-2a, GSS-2, GSS-3, GSS-4, GSS-6, GSS-8, JMS-2, GSD-6, GSD-11, GSD-12, GSD-14, GSV-2, GSB-6, GSB-14		rock, soil, sediment, plants		MC-ICP-MS		[6]
⁶⁸Zn,⁶⁶Zn, ⁶⁴Zn	SpinChem^TM, AG1-X8 (200-400 mesh)		ACR-Zn, IRMM-3702 Zn, BCR-2, BCR-2, BIR-1, BHVO-1, BHVO-2, G-2		geological reference materials, bone ash		MC-ICP-MS		[7]
⁵⁷Fe,⁵⁶Fe, ⁵⁴Fe		AGMP-1M (100-200 mesh)		KL2-G, ML3B-G, GOR128-G, GOR132-G, ATHO-G, StHs6/80-G, T1-G, BCR-2G, BHVO-2G		micrometeorites		ns-LA-MC-ICP-MS		[10]
³⁰Si,²⁹Si, ²⁸Si		-		BHVO-2, BCR-2, AGV-2, GSP-2, GSR-1, RGM-2, BHVO-2G, NIST NBS-28		bulk silicate rock		fs-LA-MC-ICP-MS		[11]
²⁰⁸Pb,²⁰⁷Pb, ²⁰⁶Pb,²⁰⁴Pb		-		NIST 610		natural water		DGT/LA-MC-ICP-MS		[12]
²⁰⁸Pb,²⁰⁷Pb, ²⁰⁶Pb		-		SA1, c3		dust samples		GC-MC-ICP-MS		[13]
⁵³Cr,⁵⁰Cr		-		SRM 979		natural water		LC-MC-ICP-MS		[14]
¹⁰⁹Ag,¹⁰⁷Ag		-		NIST SRM 978a		AgNPs, Ag⁺ ions		MC-ICP-MS		[15]
³⁰Si,²⁹Si, ²⁸Si,¹⁸O,¹⁶O		Dowex 50-X12 (200-400 mesh)		NIST SRM 8546, IRMM 017		natural and anthropogenic SiO₂ NPs		MC-ICP-MS		[16]
³⁰Si,²⁹Si,²⁸Si		Dowex 50WX8 (200-400 mesh)		IRMM-017, NIST-1648a, NIST SRM-8546		fine particulate matter		MC-ICP-MS		[17,18]
³⁰Si,²⁹Si,²⁸Si		Dowex 50-X12 (200-400 mesh)		SRM-8546, IRMM-017		fine particulate matter		MC-ICP-MS		[19]
⁵⁷Fe,⁵⁶Fe,⁵⁴Fe		AGMP-1M (100-200 mesh)		CAG-Fe		NPs extracted from pleural effusion		MC-ICP-MS		[20]
²⁰⁸Pb,²⁰⁷Pb, ²⁰⁶Pb,²⁰⁴Pb		AG1-X8 (100-200 mesh)		SRM-981, BCR-2		human whole blood samples		MC-ICP-MS		[21]
⁶⁵Cu,⁶³Cu		Cu-specific resin		SRM-986, SRM-976, AE633		mice intestinal tissues		MC-ICP-MS		[22]
⁶⁶Zn,⁶⁴Zn		AG1-X8 (200-400 mesh)		NIST SRM 1400, AZE bone		fossil teeth		MC-ICP-MS		[23]
⁴⁴Ca,⁴³Ca,⁴²Ca		AG50X-W12		NIST SRM 1486, SRM915a		human enamel		MC-ICP-MS		[24]
⁵⁷Fe,⁵⁴Fe		AG1-X4 (200-400 mesh)		IRMM-014		humic acid containing waters		MC-ICP-MS		[25]

Isotopes	Separation media		Standard material		Sample matrix		Instrumentation		Reference
¹⁰⁰Mo,⁹⁸Mo, ⁹⁷Mo,⁹⁵Mo	TRU Spec resin		NIST SRM 3134, BCR-2, BHVO-2, AGV-2, W-2, SGR-1, NOD-P-1, NOD-A-1		rock reference materials, seawater		MC-ICP-MS		[3]
¹⁰⁰Mo,⁹⁸Mo, ⁹⁷Mo,⁹⁵Mo	AG1-X8 (100-200 mesh), BPAH resin		NIST SRM 3134, BCR-2		igneous rock		MC-ICP-MS		[4]
¹¹⁴Cd,¹¹³Cd, ¹¹¹Cd,¹¹⁰Cd	AGMP-1M (100-200 mesh)		NIST 3108, BAM-I012, Spex-Cd		rock reference materials		MC-ICP-MS		[5]
⁴¹K,³⁹K	AG50W-X12 (200-400 mesh)		NIST SRM 3141a, GBW (E) 081590, BCR-2, BHVO-2, AGV-2, JG-2, GSP-2, DNC-1a, RGM-2, SDC-1, W-2a, GSS-2, GSS-3, GSS-4, GSS-6, GSS-8, JMS-2, GSD-6, GSD-11, GSD-12, GSD-14, GSV-2, GSB-6, GSB-14		rock, soil, sediment, plants		MC-ICP-MS		[6]
⁶⁸Zn,⁶⁶Zn, ⁶⁴Zn	SpinChem^TM, AG1-X8 (200-400 mesh)		ACR-Zn, IRMM-3702 Zn, BCR-2, BCR-2, BIR-1, BHVO-1, BHVO-2, G-2		geological reference materials, bone ash		MC-ICP-MS		[7]
⁵⁷Fe,⁵⁶Fe, ⁵⁴Fe		AGMP-1M (100-200 mesh)		KL2-G, ML3B-G, GOR128-G, GOR132-G, ATHO-G, StHs6/80-G, T1-G, BCR-2G, BHVO-2G		micrometeorites		ns-LA-MC-ICP-MS		[10]
³⁰Si,²⁹Si, ²⁸Si		-		BHVO-2, BCR-2, AGV-2, GSP-2, GSR-1, RGM-2, BHVO-2G, NIST NBS-28		bulk silicate rock		fs-LA-MC-ICP-MS		[11]
²⁰⁸Pb,²⁰⁷Pb, ²⁰⁶Pb,²⁰⁴Pb		-		NIST 610		natural water		DGT/LA-MC-ICP-MS		[12]
²⁰⁸Pb,²⁰⁷Pb, ²⁰⁶Pb		-		SA1, c3		dust samples		GC-MC-ICP-MS		[13]
⁵³Cr,⁵⁰Cr		-		SRM 979		natural water		LC-MC-ICP-MS		[14]
¹⁰⁹Ag,¹⁰⁷Ag		-		NIST SRM 978a		AgNPs, Ag⁺ ions		MC-ICP-MS		[15]
³⁰Si,²⁹Si, ²⁸Si,¹⁸O,¹⁶O		Dowex 50-X12 (200-400 mesh)		NIST SRM 8546, IRMM 017		natural and anthropogenic SiO₂ NPs		MC-ICP-MS		[16]
³⁰Si,²⁹Si,²⁸Si		Dowex 50WX8 (200-400 mesh)		IRMM-017, NIST-1648a, NIST SRM-8546		fine particulate matter		MC-ICP-MS		[17,18]
³⁰Si,²⁹Si,²⁸Si		Dowex 50-X12 (200-400 mesh)		SRM-8546, IRMM-017		fine particulate matter		MC-ICP-MS		[19]
⁵⁷Fe,⁵⁶Fe,⁵⁴Fe		AGMP-1M (100-200 mesh)		CAG-Fe		NPs extracted from pleural effusion		MC-ICP-MS		[20]
²⁰⁸Pb,²⁰⁷Pb, ²⁰⁶Pb,²⁰⁴Pb		AG1-X8 (100-200 mesh)		SRM-981, BCR-2		human whole blood samples		MC-ICP-MS		[21]
⁶⁵Cu,⁶³Cu		Cu-specific resin		SRM-986, SRM-976, AE633		mice intestinal tissues		MC-ICP-MS		[22]
⁶⁶Zn,⁶⁴Zn		AG1-X8 (200-400 mesh)		NIST SRM 1400, AZE bone		fossil teeth		MC-ICP-MS		[23]
⁴⁴Ca,⁴³Ca,⁴²Ca		AG50X-W12		NIST SRM 1486, SRM915a		human enamel		MC-ICP-MS		[24]
⁵⁷Fe,⁵⁴Fe		AG1-X4 (200-400 mesh)		IRMM-014		humic acid containing waters		MC-ICP-MS		[25]

多接收器电感耦合等离子体质谱方法的开发和应用进展

Recent advances in method development and application of multi-collector inductively coupled plasma mass spectrometry

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