色谱

色谱

• 专论与综述 • 上一篇    下一篇

手性环境污染物的毛细管电泳分离技术进展

楚宝临1,3,郭宝元2,王志华1,林金明2,3

  

  1. 1.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology,
    Beijing 100029, China; 2.State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research
    Center for Eco-Environmental Sciences, the Chinese Academy of Sciences, Beijing 100085, China;
    3.Department of Chemistry, Tsinghua University, Beijing 100084, China
  • 收稿日期:2007-03-27 修回日期:2007-06-15 出版日期:2007-09-30 发布日期:1985-03-25
  • 通讯作者: 林金明

Recent Advances in Enantiomeric Separation of Chiral Environmental Pollutants by Capillary Electrophoresis

CHU Baolin1,3, GUO Baoyuan2, WANG Zhihua1, LIN Jin-Ming2,3

  

  1. 1.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology,
    Beijing 100029, China; 2.State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research
    Center for Eco-Environmental Sciences, the Chinese Academy of Sciences, Beijing 100085, China;
    3.Department of Chemistry, Tsinghua University, Beijing 100084, China
  • Received:2007-03-27 Revised:2007-06-15 Online:2007-09-30 Published:1985-03-25
  • Contact: LIN Jin-Ming

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摘要：

围绕毛细管电泳(CE)技术近10年来在分离手性环境污染物方面的应用进行了介绍。对CE手性分离技术的特点做了简要概括,归纳了目前用于CE手性分离的手性选择剂。对CE技术在分离除草剂、杀虫剂、杀真菌剂以及多氯联苯(PCBs)等手性环境污染物方面的应用进行了综述,并对CE在手性环境污染物分离中的应用提出新的研究方向。

关键词: 毛细管电泳, 农药, 手性分离, 手性环境污染物, 综述

Abstract:

Capillary electrophoresis (CE) is an effective analytical tool in chiral separation. This review article is focused on the major developments in the recent applications of CE to the enantioseparation of the chiral environmental pollutants in the past decade. Developments are classified according to the types of chiral pollutants, i.e. phenoxyalkanoic acid herbicides, organophosphorus/organochlorine/pyrethroid pesticides, triazole fungicides, polychlorinated biphenyls (PCBs). The advances in enantiomeric separation of the above-mentioned chiral pollutants by CE are reviewed. In addition, the emerging chiral pollutants are highlighted and the prospects of CE in the analysis of chiral environmental pollutants are also drafted.

Key words: agrochemicals, chiral environmental pollutants, chiral separation, review , capillary electrophoresis (CE)