色谱

色谱

• 专论与综述 • 上一篇    下一篇

Lewis碱改性氧化锆基质色谱固定相的研究进展

胡玉玲1,冯钰锜2,达世禄2   

  1. 1. School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, China; 2. School of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China
  • 收稿日期:2004-07-09 修回日期:1900-01-01 出版日期:2005-05-30 发布日期:1988-09-25
  • 通讯作者: 冯钰奇
  • 基金资助:

Development of Lewis Base-Modified Zirconia as Stationary Phases for High Performance Liquid Chromatography

HU Yuling1, FENG Yuqi2, DA Shilu2   

  1. 1. School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, China; 2. School of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China
  • Received:2004-07-09 Revised:1900-01-01 Online:2005-05-30 Published:1988-09-25

PDF

574

被引次数

6

摘要： 综述了Lewis碱改性氧化锆(或其复合氧化物)基质高效液相色谱填料的研究进展,涉及的改性剂包括氟离子、磷酸盐、有机膦酸、羧酸、酚类化合物、蛋白质和环糊精衍生物等。简要介绍了Lewis碱改性氧化锆固定相在毛细管电色谱中的应用。 引用文献51篇。

关键词: Lewis碱, 高效液相色谱, 固定相, 氧化锆, 综述

Abstract: The developments of the Lewis base-modified zirconia and mixed-oxide containing zirconia as stationary phases for high performance liquid chromatography (HPLC) are reviewed. Zirconia supports for HPLC based on modification with fluoride, phosphate, phosphonate, carboxylic acid, phenols, and protein, as well as cyclodextrin derivative, are covered. The application of modified-zirconia in capillary electrochromatography (CEC) is also discussed. Fifty-one references are cited.

Key words: high performance liquid chromatography, stationary phase, zirconia, Lewis base, review