色谱

色谱 ›› 2016, Vol. 34 ›› Issue (3): 346-350.DOI: 10.3724/SP.J.1123.2015.10022

• 研究论文 • 上一篇    下一篇

混合氯化石蜡中短链氯化石蜡定量分析方法的比较

幸苑娜, 冯岸红, 叶淋泉, 林志惠, 陈茜, 陈泽勇   

  1. 深圳市计量质量检测研究院, 广东 深圳 518131
  • 收稿日期:2015-10-15 出版日期:2016-03-08 发布日期:2012-09-28
  • 通讯作者: 冯岸红
  • 基金资助:

    广东省质量技术监督局科技项目(2013PJ03).

Comparison of quantitative analytical methods of short chain chlorinated paraffins in chlorinated paraffin mixtures

XING Yuanna, FENG Anhong, YE Linquan, LIN Zhihui, CHEN Qian, CHEN Zeyong   

  1. Shenzhen Academy of Metrology and Quality Inspection, Shenzhen 518131, China
  • Received:2015-10-15 Online:2016-03-08 Published:2012-09-28
  • Supported by:

    Technology Project of Administration of Quality and Technology Supervision of Guangdong Province(No. 2013PJ03).

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123

被引次数

2

摘要：

分别采用总体响应因子校正法和多元线性回归法对混合氯化石蜡中短链氯化石蜡进行定量分析,结果表明:两种方法均能较好地排除中链氯化石蜡的干扰,从而提高了短链氯化石蜡的定量准确性;但是两种方法均对标准曲线的浓度范围存在一定的依赖性,在使用这两种方法进行定量分析时,应将样品稀释到标准曲线适用的浓度范围。另外,相对于总体响应因子校正法,多元线性回归法定量范围更广。

关键词: 短链氯化石蜡, 多元线性回归法, 总体响应因子校正法

Abstract:

Total response factor correction method and multiple linear regression method were adopted to quantify the sum of short chain chlorinated paraffins (SCCPs) in chlorinated paraffin mixtures. Both methods were based on electron capture negative ionization mass spectrometry. The results showed that high SCCPs quantitative accuracies were obtained by the two methods both with eliminating the potential interferences of mediumchain chlorinated paraffins. However, both two methods were slightly dependent on the ranges of calibration solutions. Dilution of the sample solution was necessary when performing these two methods. Besides, multiple linear regression method was suitable for more wide-quantitative-range of SCCPs than total response factor correction method.

Key words: multiple linear regression method, short chain chlorinated paraffins (SCCPs), total response factor correction method

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