Determination of solubility parameters and the related thermodynamic properties of polyvinyl alcohol using inverse gas chromatography and Hansen solubility parameters

doi:10.3724/SP.J.1123.2016.05015

Abstract

Abstract:

An inverse gas chromatography (IGC) method was used to study the solubility parameters (δ₂) and the related thermodynamic properties of polyvinyl alcohol (PVA) that was used for the stationary phase. Totally 5 classes of 18 organic solvent molecules (aliphatic, aromatic hydrocarbons, alcohols, ketones and halohydrocarbons) were used for the probe molecules at 383.15-423.15 K. And the δ₂ was compared with the solubility parameter (δ_T) that was measured by the Hansen solubility parameter (HSP) method. The results showed that the solving ability of PVA decreased in the 5 classes of solvents in the following sequence: ketones > alcohols > halohydrocarbons, aromatic hydrocarbons, aliphatics >alicyclics, and the halohydrocarbons, aromatic hydrocarbons, aliphatics had similar solving abilities. The δ₂ increased with the increase of temperature at 383.15-423.15 K. The δ₂ of PVA that was derived as 27.69 (J/cm³)^0.5 by analytical extrapolation method at room temperature (298.15 K) was consistent with the δ_T of PVA that was measured as 27.77 (J/cm³)^0.5 by the HSP method at room temperature. The determination of solubility parameters and the related thermodynamic parameters can be used as a reference to the application and research of PVA.

Key words: Hansen solubility parameters (HSP), inverse gas chromatography (IGC), polyvinyl alcohol (PVA), solubility parameters

CLC Number:

O658

NI Haiyue, REN Shixue, FANG Guizhen, MA Yanli. Determination of solubility parameters and the related thermodynamic properties of polyvinyl alcohol using inverse gas chromatography and Hansen solubility parameters[J]. Chinese Journal of Chromatography, 2016, 34(9): 933-939.

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