Determination of anion impurities in barium carbonate by ion chromatography with membrane treatment

doi:10.3724/SP.J.1123.2016.01026

Chinese Journal of Chromatography ›› 2016, Vol. 34 ›› Issue (5): 498-501.DOI: 10.3724/SP.J.1123.2016.01026

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Determination of anion impurities in barium carbonate by ion chromatography with membrane treatment

ZHU Binhe^1,2, ZHANG Peimin¹, GUO Weiqiang¹, LI Gang³, JIANG Xinhua⁴, WU Shuchao⁵, ZHU Yan^1,2

1. Department of Chemistry, Zhejiang University, Hangzhou 310028, China;
2. Zhejiang Provincial Key Laboratory of Health Risk Appraisal for Trace Toxic Chemicals, Zhejiang University, Hangzhou 310028, China;
3. Shaoxing Environmental Monitoring Station, Shaoxing 312000, China;
4. Juhua Hospital, Quzhou 324004, China;
5. Zhejiang Institute of Geology and Mineral Resources, Hangzhou 310007, China

Received:2016-01-19 Online:2016-05-08 Published:2012-12-18
Supported by:
National Natural Science Foundation of China (No. 21405141); National Important Project on Science Instrument (No. 2012YQ09022903); Zhejiang Provincial Natural Science Foundation (Nos. LZ16B050001, LY15B050001, S16H180002).

Abstract

Abstract:

An ion chromatographic (IC) method with membrane treatment was developed for the simultaneous determination of anions (F^-, SO₄^2- and NO₃^-) in barium carbonate. The cation exchange membrane was applied in providing H⁺ in hydrochloric acid to dissolve barium carbonate and to prevent anions dissolving into the solution from hydrochloric acid. After pre-treatment by acid dissolution and membrane treatment, the sample was diluted for 100 times and filtrated by a 0.22 μ m membrane, then analyzed by IC using 20 mmol/L KOH as the eluent. The target anions were separated by an Ion Pac AG11-HC (50 mm×4 mm) and an Ion Pac AS11-HC (250 mm×4 mm) ion-exchange columns and detected by suppressed conductivity detection with 50 mA current. Under the optimized separation conditions, the calibration curves showed good linearity (R²≥0.9996) in the range of 0.01-5.00 mg/L. The limits of detection were in the range of 1.37-9.45 μ g/L with the relative standard deviations (RSDs) of 1.87%-2.19%. The recoveries of F^-, SO₄^2- and NO₃^- anions were between 84.0% and 106.2%. This method can determine the three inorganic anions (F^-, SO₄^2- and NO₃^-) in barium carbonate fast and accurately. It is suitable for the simultaneous separation and detection of trace inorganic anions in insoluble products.

Key words: anions, barium carbonate, ion chromatography (IC), membrane treatment

CLC Number:

O658

ZHU Binhe, ZHANG Peimin, GUO Weiqiang, LI Gang, JIANG Xinhua, WU Shuchao, ZHU Yan. Determination of anion impurities in barium carbonate by ion chromatography with membrane treatment[J]. Chinese Journal of Chromatography, 2016, 34(5): 498-501.

References

[1] Chen Y J, Wang H. Modern Chemical Industry, 2002, 22(5): 53 陈英军, 王缓. 现代化工, 2002, 22(5): 53
[2] Merie V, Candea V, Popa C T. Adv Eng Froum, 2015, 13: 67
[3] Fernandes J P, Duarte G W, Caldart C, et al. J Alloy Compd, 2015, 649: 809
[4] Carmona-Quiroga P M, Blanco-Varela M T. Cement Concrete Res, 2015, 69: 96
[5] Hong T, Chen F, Xia C. J Power Sources, 2015, 278: 741
[6] Yoon S E, Ahn J Y, Park J S. J Korean Ceram Soc, 2015, 52(5): 350
[7] Zhang J, Zhang S H. China Chlor-Alkali, 2007(5): 10 张坚, 张素环. 中国氯碱, 2007(5): 10
[8] Luan X M, Wang J, Shang S M. Physical Testing and Chemical Analysis Part B: Chemical Analysis, 2009, 45(9): 1056 栾雪梅, 王璟, 商少明. 理化检验-化学分册, 2009, 45(9): 1056
[9] Zhang C. Physical Testing and Chemical Analysis Part B: Chemical Analysis, 1999, 35(12): 571 张嫦. 理化检验-化学分册, 1999, 35(12): 571
[10] Yamamoto Y, Azuma T, Nishimura Y, et al. Jpn Analyst, 1986, 35(8): 631
[11] Liu X G, Gao S, Hu S H, et al. Metallurgical Analysis, 2002, 22(4): 44 刘先国, 高山, 胡圣虹, 等. 冶金分析, 2002, 22(4): 44
[12] Zhu Z M, Du Z G, Ge H B. Physical Testing and Chemical Analysis Part B: Chemical Analysis, 2010, 46(9): 1037 朱泽民, 杜治国, 葛恒波. 理化检验-化学分册, 2010, 46(9): 1037
[13] Huang Z P, Wu H W, Wang F L, et al. J Chromatogr A, 2013, 1294: 152
[14] Yang Y L, He J, Huang Z P, et al. J Chromatogr A, 2013, 1305: 171
[15] Cui H, Mou Z C, Mao X B, et al. Chinese Journal of Analytical Chemistry, 2002, 30(8): 1020 崔鹤, 牟志春, 毛旭斌, 等. 分析化学, 2002, 30(8): 1020
[16] He P, Deng J H. Journal of Food Safety & Quality, 2015, 6(2): 673 何攀, 邓洁红. 食品安全质量检测学报, 2015, 6(2): 673

Determination of anion impurities in barium carbonate by ion chromatography with membrane treatment

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