Advances of poly(ionic liquid) materials in separation science

doi:10.3724/SP.J.1123.2015.07033

Abstract

Abstract:

Ionic liquids, as novel ionization reagents, possess beneficial characteristics including good solubility, conductivity, thermal stability, biocompatibility, low volatility and non-flammability. Ionic liquids are attracting a mass of attention of analytical chemists. Poly(ionic liquid) materials have common performances of ionic liquids and polymers, and have been successfully applied in separation science area. In this paper, we discuss the interaction mechanisms between the poly(ionic liquid) materials and analytes including hydrophobic/hydrophilic interactions, hydrogen bond, ion exchange, π - π stacking and electrostatic interactions, and summarize the application advances of the poly(ionic liquid) materials in solid phase extraction, chromatographic separation and capillary electrophoresis. At last, we describe the future prospect of poly(ionic liquid) materials.

Key words: capillary electrophoresis, chromatographic separation, interaction mechanisms, poly(ionic liquid) materials, solid phase extraction

CLC Number:

O658

LIU Cuicui, GUO Ting, SU Rina, GU Yuchen, DENG Qiliang. Advances of poly(ionic liquid) materials in separation science[J]. Chinese Journal of Chromatography, 2015, 33(11): 1126-1133.

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