Determination of diethyl aminoethyl hexanoate residues in apples by gas chromatography-mass spectrometry combined with improved QuEChERS

doi:10.3724/SP.J.1123.2019.08021

Abstract

Abstract: A method was developed for the determination of diethyl aminoethyl hexanoate (DA-6) residues in apples by gas chromatography-mass spectrometry (GC-MS) combined with improved QuEChERS. The samples were first extracted with warm water, then, the extract was subjected to liquid-liquid re-extraction with dichloromethane, followed by rotary evaporation concentration. The residues were cleaned up with primary secondary amine (PSA). The analytes were separated on an HP-5 capillary column and detected using an EI source in the SIM mode. The recoveries ranged from 74.1% to 84.2% at three spiked levels, with relative standard deviations (RSDs) between 1.5% and 4.1%. The limit of detection and limit of quantification were 0.0024 mg/kg and 0.008 mg/kg, respectively. The developed method is sensitive, and practically applicable for the determination of DA-6 residues in apple samples.

Key words: gas chromatography-mass spectrometry (GC-MS), QuEChERS, diethyl aminoethyl hexanoate (DA-6), apple

CLC Number:

O658

KONG Xiangji, KONG Shun, ZHANG Xuemei, KONG Deyang. Determination of diethyl aminoethyl hexanoate residues in apples by gas chromatography-mass spectrometry combined with improved QuEChERS[J]. Chinese Journal of Chromatography, 2019, 37(12): 1363-1367.

References

[1] Nie L X, Jiang X Y, Wu S H, et al. Chinese Journal of Applied Ecology, 2010, 21(10):2558 聂乐兴, 姜兴印, 吴淑华, 等. 应用生态学报, 2010, 21(10):2558
[2] Nie L X, Jiang X Y, Wu S H, et al. Journal of Maize Sciences, 2010, 18(6):33 聂乐兴, 姜兴印, 吴淑华, 等. 玉米科学, 2010, 18(6):33
[3] Pan Z M, Zhou L M, Huang Q, et al. World Science-Technology Research & Development, 2015(2):134 潘志明, 周路明, 黄琼, 等. 世界科技研究与发展, 2015(2):134
[4] Liang X L, Fang S M, Hu B X, et al. Hubei Agricultural Sciences, 2011, 50(7):1325 梁喜龙, 方淑梅, 胡百兴, 等. 湖北农业科学, 2011, 50(7):1325
[5] Wang C L, Jing H, Xue C, et al. Pesticide Science and Administration, 2002, 23(5):10 王彩玲, 景辉, 薛超, 等. 农药科学与管理, 2002, 23(5):10
[6] Qiao G F, Chen P, Bao H F. Henan Chemical Industry, 2008, 25(1):48 乔桂芳, 陈平, 保海防. 河南化工, 2008, 25(1):48
[7] Guo M, Shi L L, Shan Z J, et al. Journal of Ecology and Rural Environment, 2007, 23(4):45 郭敏, 石利利, 单正军, 等. 生态与农村环境学报, 2007, 23(4):45
[8] Xie L Q, Jiang S R, Xu P J, et al. Food Science, 2008, 29(4):338 谢柳青, 江树人, 许鹏军, 等. 食品科学, 2008, 29(4):338
[9] Liang L, Bao R, Jiang J Z, et al. Chinese Journal of Pesticide Science, 2011, 13(1):99 梁林, 薄瑞, 蒋家珍, 等. 农药学学报, 2011, 13(1):99
[10] Zhao L, Li X J, Qiu J, et al. Soils and Fertilizers Sciences in China, 2014(4):102 赵鲁, 李旭军, 邱静, 等. 中国土壤与肥料, 2014(4):102
[11] Peng S Y, He J, Yan Y Q. China Patent, 201611053041.2. 2017-04-26 彭山英, 何颉, 颜亚奇. 中国专利, 201611053041.2. 2017-04-26
[12] Deng H F, Zhang J Y, Huang K, et al. Chinese Journal of Chromatography, 2018(12):1211 邓慧芬, 张建莹, 黄科, 等. 色谱, 2018(12):1211
[13] Cui L L, Yan M X, Piao X M, et al. Chinese Journal of Chromatography, 2018, 36(11):111 崔丽丽, 闫梅霞, 朴向民, 等. 色谱, 2018, 36(11):111
[14] Zhang K, Qin Y, Bian H, et al. Chinese Journal of Chromatography, 2018, 36(10):65 张凯, 秦宇, 卞华, 等. 色谱, 2018, 36(10):65
[15] Huang B Y, Ouyang X H, Pan C P. Chinese Journal of Pesticide Science, 2005, 7(4):299 黄宝勇, 欧阳喜辉, 潘灿平. 农药学学报, 2005, 7(4):299