Chinese Journal of Chromatography ›› 2021, Vol. 39 ›› Issue (11): 1222-1229.DOI: 10.3724/SP.J.1123.2020.11020
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ZUO Xue, DI Zheng, DU Yong, YANG Ling, ZHANG Rong, WU Guoqing*()
Received:
2020-12-22
Online:
2021-11-08
Published:
2021-03-25
Contact:
WU Guoqing
CLC Number:
ZUO Xue, DI Zheng, DU Yong, YANG Ling, ZHANG Rong, WU Guoqing. Determination of 40 dyes in oxidative hair dye products by high performance liquid chromatography[J]. Chinese Journal of Chromatography, 2021, 39(11): 1222-1229.
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URL: https://www.chrom-china.com/EN/10.3724/SP.J.1123.2020.11020
No. | tR/min | Compound |
---|---|---|
1 | 3.550 | 1-hydroxyethyl 4,5-diaminopyrazole sulfate (1-羟乙基-4,5-二氨基吡唑硫酸盐) |
2 | 3.894 | tetraaminopyrimidine sulfate (四氨基嘧啶硫酸盐) |
3 | 5.472 | 2-amino-3-hydroxypyridine (2-氨基-3-羟基吡啶) |
4 | 5.910 | p-phenylenediamine (对苯二胺) |
5 | 6.608 | hydroxyethyl-p-phenylenediaminesulfate (羟乙基对苯二胺硫酸盐) |
6 | 7.650 | p-aminophenol (对氨基苯酚) |
7 | 9.410 | 2,6-diaminopyridine (2,6-二氨基吡啶) |
8 | 9.945 | m-phenylenediamine (间苯二胺) |
9 | 10.280 | hydroquinone (氢醌) |
10 | 11.035 | toluene-2,5-diamine sulfate (甲苯-2,5-二胺硫酸盐) |
11 | 12.433 | 2,4-diaminophenoxyethanol HCl (2,4-二氨基苯氧基乙醇盐酸盐) |
12 | 13.198 | m-aminophenol (间氨基苯酚) |
13 | 14.916 | 4-amino-m-cresol (4-氨基间甲酚) |
14 | 17.741 | o-phenylenediamine (邻苯二胺) |
15 | 19.567 | resorcinol (间苯二酚) |
16 | 20.352 | o-aminophenol (邻氨基苯酚) |
17 | 22.257 | 2-chloro-p-phenylenediamine sulfate (2-氯-对苯二胺硫酸盐) |
18 | 23.063 | N,N-bis(2-hydroxyethyl)-p-phenylenediamine sulfate (N,N-双(2-羟乙基)-对苯二胺硫酸盐) |
19 | 24.357 | 2-methylresorcinol (2-甲基间苯二酚) |
20 | 29.024 | 2-amino-6-chloro-4-nitrophenol (2-氨基-6-氯-4-硝基苯酚) |
21 | 34.799 | hydroxybenzomorpholine (羟苯并吗啉) |
22 | 38.056 | 4-amino-2-hydroxytoluene (4-氨基-2-羟基甲苯) |
23 | 38.803 | 4-nitro-o-phenylenediamine (4-硝基邻苯二胺) |
24 | 39.508 | 4-amino-3-nitrophenol (4-氨基-3-硝基苯酚) |
25 | 41.934 | 6-amino-m-cresol (6-氨基间甲酚) |
26 | 43.979 | 2,6-dihydroxyethylaminotoluene (2,6-二羟乙基氨甲苯) |
27 | 45.960 | 3-nitro-p-hydroxyethylaminophenol (3-硝基对羟乙氨基酚) |
28 | 46.662 | 2-methyl-5-hydroxyethylaminophenol (2-甲基-5-羟乙氨基苯酚) |
29 | 47.630 | pyrazolone methyl pyrazolone (苯基甲基吡唑啉酮) |
30 | 50.582 | 4-chlororesorcinol (4-氯间苯二酚) |
31 | 51.254 | 6-hydroxyindole (6-羟基吲哚) |
32 | 52.596 | 5-amino-6-chloro-o-cresol (5-氨基-6-氯-邻甲酚) |
33 | 53.513 | 4-hydroxypropylamino-3-nitrophenol (4-羟丙氨基-3-硝基苯酚) |
34 | 55.264 | 1,5-naphthalenediol (1,5-萘二酚) |
35 | 58.122 | 2,7-naphthalenediol (2,7-萘二酚) |
36 | 60.632 | HC yellow No.2 (HC黄2号) |
37 | 61.270 | 5-amino-4-chloro-o-cresol (5-氨基-4-氯邻甲酚) |
38 | 62.577 | hydroxyethyl-2-nitro-p-toluidine (羟乙基-2-硝基对甲苯胺) |
39 | 63.169 | N-phenyl-p-phenylenediamine (N-苯基-对苯二胺) |
40 | 63.735 | 1-naphthol (1-萘酚) |
Table 1 Information of the 40 dye standard substances
No. | tR/min | Compound |
---|---|---|
1 | 3.550 | 1-hydroxyethyl 4,5-diaminopyrazole sulfate (1-羟乙基-4,5-二氨基吡唑硫酸盐) |
2 | 3.894 | tetraaminopyrimidine sulfate (四氨基嘧啶硫酸盐) |
3 | 5.472 | 2-amino-3-hydroxypyridine (2-氨基-3-羟基吡啶) |
4 | 5.910 | p-phenylenediamine (对苯二胺) |
5 | 6.608 | hydroxyethyl-p-phenylenediaminesulfate (羟乙基对苯二胺硫酸盐) |
6 | 7.650 | p-aminophenol (对氨基苯酚) |
7 | 9.410 | 2,6-diaminopyridine (2,6-二氨基吡啶) |
8 | 9.945 | m-phenylenediamine (间苯二胺) |
9 | 10.280 | hydroquinone (氢醌) |
10 | 11.035 | toluene-2,5-diamine sulfate (甲苯-2,5-二胺硫酸盐) |
11 | 12.433 | 2,4-diaminophenoxyethanol HCl (2,4-二氨基苯氧基乙醇盐酸盐) |
12 | 13.198 | m-aminophenol (间氨基苯酚) |
13 | 14.916 | 4-amino-m-cresol (4-氨基间甲酚) |
14 | 17.741 | o-phenylenediamine (邻苯二胺) |
15 | 19.567 | resorcinol (间苯二酚) |
16 | 20.352 | o-aminophenol (邻氨基苯酚) |
17 | 22.257 | 2-chloro-p-phenylenediamine sulfate (2-氯-对苯二胺硫酸盐) |
18 | 23.063 | N,N-bis(2-hydroxyethyl)-p-phenylenediamine sulfate (N,N-双(2-羟乙基)-对苯二胺硫酸盐) |
19 | 24.357 | 2-methylresorcinol (2-甲基间苯二酚) |
20 | 29.024 | 2-amino-6-chloro-4-nitrophenol (2-氨基-6-氯-4-硝基苯酚) |
21 | 34.799 | hydroxybenzomorpholine (羟苯并吗啉) |
22 | 38.056 | 4-amino-2-hydroxytoluene (4-氨基-2-羟基甲苯) |
23 | 38.803 | 4-nitro-o-phenylenediamine (4-硝基邻苯二胺) |
24 | 39.508 | 4-amino-3-nitrophenol (4-氨基-3-硝基苯酚) |
25 | 41.934 | 6-amino-m-cresol (6-氨基间甲酚) |
26 | 43.979 | 2,6-dihydroxyethylaminotoluene (2,6-二羟乙基氨甲苯) |
27 | 45.960 | 3-nitro-p-hydroxyethylaminophenol (3-硝基对羟乙氨基酚) |
28 | 46.662 | 2-methyl-5-hydroxyethylaminophenol (2-甲基-5-羟乙氨基苯酚) |
29 | 47.630 | pyrazolone methyl pyrazolone (苯基甲基吡唑啉酮) |
30 | 50.582 | 4-chlororesorcinol (4-氯间苯二酚) |
31 | 51.254 | 6-hydroxyindole (6-羟基吲哚) |
32 | 52.596 | 5-amino-6-chloro-o-cresol (5-氨基-6-氯-邻甲酚) |
33 | 53.513 | 4-hydroxypropylamino-3-nitrophenol (4-羟丙氨基-3-硝基苯酚) |
34 | 55.264 | 1,5-naphthalenediol (1,5-萘二酚) |
35 | 58.122 | 2,7-naphthalenediol (2,7-萘二酚) |
36 | 60.632 | HC yellow No.2 (HC黄2号) |
37 | 61.270 | 5-amino-4-chloro-o-cresol (5-氨基-4-氯邻甲酚) |
38 | 62.577 | hydroxyethyl-2-nitro-p-toluidine (羟乙基-2-硝基对甲苯胺) |
39 | 63.169 | N-phenyl-p-phenylenediamine (N-苯基-对苯二胺) |
40 | 63.735 | 1-naphthol (1-萘酚) |
Time/min | φ(A)/% | φ(B)/% | Column temperature/ ℃ |
---|---|---|---|
0 | 100 | 0 | 30 |
25 | 100 | 0 | 30 |
25.1 | 100 | 0 | 35 |
30 | 95 | 5 | 35 |
38 | 90 | 10 | 35 |
47 | 87 | 13 | 35 |
55 | 75 | 25 | 35 |
60 | 35 | 65 | 35 |
61 | 100 | 0 | 30 |
67 | 100 | 0 | 30 |
Table 2 HPLC gradient elution procedure
Time/min | φ(A)/% | φ(B)/% | Column temperature/ ℃ |
---|---|---|---|
0 | 100 | 0 | 30 |
25 | 100 | 0 | 30 |
25.1 | 100 | 0 | 35 |
30 | 95 | 5 | 35 |
38 | 90 | 10 | 35 |
47 | 87 | 13 | 35 |
55 | 75 | 25 | 35 |
60 | 35 | 65 | 35 |
61 | 100 | 0 | 30 |
67 | 100 | 0 | 30 |
Fig. 1 Chromatograms of dyes in the mixed standard solution using different mobile phases Mobile phases: for (a) and (c), (A) 0.02 mol/L ammonium acetate aqueous solution (containing 4% ACN) and (B) ACN; for (b) and (d), (A) 0.04 mol/L potassium dihydrogen phosphate and 0.01 mol/L disodium hydrogen phosphate (containing 4% ACN) and (B) ACN. Gradient elution procedure: 0-25 min, 0%B; 25-42 min, 0%B-14%B; 42-46 min, 14%B-40%B; 46-56 min, 40%B-60%B; 56-58 min, 60%B-0%B; 58-63 min, 0%B. Column temperature: 35 ℃; detection wavelength: 235 nm.
No. | Regression equation | Linear range/ (mg/L) | r | LOD/ (μg/g) | LOQ/ (μg/g) | 2.5 mg/g | 5.0 mg/g | 10 mg/g | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Recovery/% | RSD/% | Recovery/% | RSD/% | Recovery/% | RSD/% | |||||||||
1 | A=3.863C-13.43 | 5-500 | 0.9999 | 81 | 272 | 100.8 | 1.8 | 98.8 | 1.1 | 105.3 | 0.7 | |||
2 | A=9.655C-42.96 | 5-500 | 0.9999 | 50 | 167 | 98.7 | 0.8 | 101.2 | 0.6 | 99.6 | 0.3 | |||
3 | A=7.604C-3.328 | 5-500 | 0.9999 | 50 | 167 | 109.6 | 2.6 | 105.2 | 0.8 | 102.4 | 0.6 | |||
4 | A=22.08C+8.847 | 5-500 | 0.9999 | 50 | 168 | 101.8 | 0.6 | 103.5 | 0.5 | 100.5 | 0.9 | |||
5 | A=8.821C-9.130 | 5-500 | 0.9999 | 48 | 160 | 103.5 | 1.8 | 98.6 | 0.8 | 105.1 | 0.7 | |||
6 | A=16.24C+13.34 | 5-500 | 0.9999 | 25 | 84 | 95.5 | 3.6 | 94.2 | 1.0 | 93.8 | 1.4 | |||
7 | A=17.30C+1.879 | 5-500 | 0.9999 | 25 | 84 | 102.6 | 3.1 | 99.8 | 0.5 | 97.8 | 0.8 | |||
8 | A=21.40C+45.94 | 5-500 | 0.9999 | 10 | 33 | 103.0 | 2.3 | 102.3 | 0.4 | 100.1 | 0.9 | |||
9 | A=4.581C+5.838 | 5-500 | 0.9999 | 50 | 167 | 98.3 | 0.5 | 101.0 | 0.9 | 99.2 | 0.4 | |||
10 | A=9.828C+11.59 | 5-500 | 0.9999 | 25 | 83 | 100.7 | 1.5 | 101.8 | 0.4 | 98.6 | 0.9 | |||
11 | A=9.842C+2.185 | 5-500 | 0.9999 | 25 | 83 | 98.7 | 0.9 | 99.9 | 0.6 | 98.5 | 0.9 | |||
12 | A=17.08C+17.03 | 5-500 | 0.9999 | 10 | 34 | 105.1 | 3.9 | 99.4 | 0.6 | 97.4 | 0.9 | |||
13 | A=12.66C+10.48 | 5-500 | 0.9998 | 25 | 84 | 101.9 | 1.0 | 87.0 | 2.0 | 86.5 | 1.9 | |||
14 | A=16.16C+5.680 | 5-500 | 0.9999 | 10 | 33 | 106.0 | 2.3 | 100.0 | 0.5 | 98.8 | 0.8 | |||
15 | A=4.156C-0.3880 | 5-500 | 0.9998 | 50 | 166 | 102.6 | 2.6 | 94.8 | 1.8 | 92.9 | 1.3 | |||
16 | A=15.25C+12.51 | 5-500 | 0.9999 | 25 | 83 | 102.9 | 3.6 | 98.2 | 1.1 | 95.6 | 1.0 | |||
17 | A=8.834C+6.080 | 5-500 | 0.9999 | 50 | 168 | 98.8 | 0.4 | 100.1 | 0.5 | 97.8 | 1.2 | |||
18 | A=4.890C+0.5869 | 10-500 | 0.9999 | 168 | 504 | 100.5 | 0.8 | 103.6 | 1.7 | 101.7 | 1.2 | |||
19 | A=4.119C+6.583 | 5-500 | 0.9999 | 84 | 279 | 95.4 | 2.3 | 92.6 | 2.4 | 90.4 | 1.5 | |||
20 | A=15.97C-5.058 | 5-500 | 0.9999 | 50 | 165 | 101.6 | 3.5 | 96.5 | 1.0 | 93.3 | 0.8 | |||
21 | A=9.363C+7.574 | 5-500 | 0.9999 | 25 | 84 | 102.1 | 4.0 | 97.4 | 1.4 | 95.7 | 1.1 | |||
22 | A=15.52C+13.09 | 5-500 | 0.9999 | 25 | 83 | 104.3 | 1.9 | 98.0 | 1.2 | 96.1 | 0.5 | |||
23 | A=13.42C+18.91 | 5-500 | 0.9999 | 25 | 82 | 93.5 | 1.1 | 88.9 | 3.2 | 101.8 | 0.2 | |||
24 | A=29.03C+33.56 | 5-500 | 0.9999 | 10 | 34 | 96.3 | 2.1 | 104.2 | 1.0 | 105.9 | 0.6 | |||
25 | A=13.36C+21.38 | 5-500 | 0.9999 | 25 | 84 | 96.4 | 3.5 | 95.8 | 1.4 | 93.8 | 1.2 | |||
26 | A=27.47C+32.53 | 5-250 | 0.9999 | 5 | 17 | 97.6 | 1.0 | 102.3 | 0.4 | 99.5 | 0.9 | |||
27 | A=27.26C+36.18 | 5-500 | 0.9999 | 10 | 33 | 96.3 | 0.3 | 93.0 | 2.8 | 89.9 | 2.2 | |||
28 | A=13.43C+11.58 | 5-500 | 0.9999 | 25 | 83 | 95.6 | 0.4 | 98.2 | 0.8 | 96.1 | 1.0 | |||
29 | A=15.09C+16.83 | 5-500 | 0.9999 | 50 | 165 | 99.0 | 1.9 | 99.7 | 0.9 | 93.3 | 0.5 | |||
30 | A=7.479C+10.23 | 5-500 | 0.9999 | 50 | 166 | 94.5 | 1.6 | 95.9 | 1.8 | 101.2 | 0.7 | |||
31 | A=8.930C+11.22 | 5-500 | 0.9999 | 50 | 166 | 100.2 | 1.8 | 103.2 | 1.9 | 106.2 | 1.0 | |||
32 | A=13.91C+18.68 | 5-500 | 0.9999 | 50 | 165 | 92.6 | 0.4 | 92.5 | 0.3 | 96.5 | 0.5 | |||
33 | A=25.45C+40.23 | 5-500 | 0.9999 | 10 | 34 | 95.0 | 0.2 | 97.1 | 0.9 | 100.9 | 0.3 | |||
34 | A=7.039C+4.692 | 5-500 | 0.9999 | 25 | 84 | 94.9 | 1.1 | 100.0 | 0.7 | 99.5 | 0.6 | |||
35 | A=5.679C+6.342 | 5-500 | 0.9999 | 25 | 83 | 90.4 | 0.9 | 91.7 | 1.1 | 92.9 | 1.4 | |||
36 | A=6.771C+7.516 | 5-500 | 0.9999 | 10 | 34 | 96.0 | 0.8 | 97.8 | 1.0 | 102.5 | 2.4 | |||
37 | A=2.318C+0.4190 | 5-500 | 0.9999 | 25 | 82 | 91.5 | 0.8 | 92.4 | 1.7 | 94.9 | 1.1 | |||
38 | A=6.514C+8.196 | 5-500 | 0.9999 | 5 | 17 | 90.0 | 0.5 | 91.0 | 1.0 | 94.9 | 2.0 | |||
39 | A=23.44C+43.40 | 5-250 | 0.9998 | 5 | 16 | 89.8 | 3.2 | 90.8 | 2.1 | 94.0 | 1.8 | |||
40 | A=7.160C+1.060 | 5-500 | 0.9999 | 5 | 17 | 81.4 | 1.8 | 87.4 | 2.2 | 88.8 | 2.1 |
Table 3 Regression equations, linear ranges, correlation coefficients (r), LODs, LOQs and spiked recoveries for the 40 dyes (n=3)
No. | Regression equation | Linear range/ (mg/L) | r | LOD/ (μg/g) | LOQ/ (μg/g) | 2.5 mg/g | 5.0 mg/g | 10 mg/g | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Recovery/% | RSD/% | Recovery/% | RSD/% | Recovery/% | RSD/% | |||||||||
1 | A=3.863C-13.43 | 5-500 | 0.9999 | 81 | 272 | 100.8 | 1.8 | 98.8 | 1.1 | 105.3 | 0.7 | |||
2 | A=9.655C-42.96 | 5-500 | 0.9999 | 50 | 167 | 98.7 | 0.8 | 101.2 | 0.6 | 99.6 | 0.3 | |||
3 | A=7.604C-3.328 | 5-500 | 0.9999 | 50 | 167 | 109.6 | 2.6 | 105.2 | 0.8 | 102.4 | 0.6 | |||
4 | A=22.08C+8.847 | 5-500 | 0.9999 | 50 | 168 | 101.8 | 0.6 | 103.5 | 0.5 | 100.5 | 0.9 | |||
5 | A=8.821C-9.130 | 5-500 | 0.9999 | 48 | 160 | 103.5 | 1.8 | 98.6 | 0.8 | 105.1 | 0.7 | |||
6 | A=16.24C+13.34 | 5-500 | 0.9999 | 25 | 84 | 95.5 | 3.6 | 94.2 | 1.0 | 93.8 | 1.4 | |||
7 | A=17.30C+1.879 | 5-500 | 0.9999 | 25 | 84 | 102.6 | 3.1 | 99.8 | 0.5 | 97.8 | 0.8 | |||
8 | A=21.40C+45.94 | 5-500 | 0.9999 | 10 | 33 | 103.0 | 2.3 | 102.3 | 0.4 | 100.1 | 0.9 | |||
9 | A=4.581C+5.838 | 5-500 | 0.9999 | 50 | 167 | 98.3 | 0.5 | 101.0 | 0.9 | 99.2 | 0.4 | |||
10 | A=9.828C+11.59 | 5-500 | 0.9999 | 25 | 83 | 100.7 | 1.5 | 101.8 | 0.4 | 98.6 | 0.9 | |||
11 | A=9.842C+2.185 | 5-500 | 0.9999 | 25 | 83 | 98.7 | 0.9 | 99.9 | 0.6 | 98.5 | 0.9 | |||
12 | A=17.08C+17.03 | 5-500 | 0.9999 | 10 | 34 | 105.1 | 3.9 | 99.4 | 0.6 | 97.4 | 0.9 | |||
13 | A=12.66C+10.48 | 5-500 | 0.9998 | 25 | 84 | 101.9 | 1.0 | 87.0 | 2.0 | 86.5 | 1.9 | |||
14 | A=16.16C+5.680 | 5-500 | 0.9999 | 10 | 33 | 106.0 | 2.3 | 100.0 | 0.5 | 98.8 | 0.8 | |||
15 | A=4.156C-0.3880 | 5-500 | 0.9998 | 50 | 166 | 102.6 | 2.6 | 94.8 | 1.8 | 92.9 | 1.3 | |||
16 | A=15.25C+12.51 | 5-500 | 0.9999 | 25 | 83 | 102.9 | 3.6 | 98.2 | 1.1 | 95.6 | 1.0 | |||
17 | A=8.834C+6.080 | 5-500 | 0.9999 | 50 | 168 | 98.8 | 0.4 | 100.1 | 0.5 | 97.8 | 1.2 | |||
18 | A=4.890C+0.5869 | 10-500 | 0.9999 | 168 | 504 | 100.5 | 0.8 | 103.6 | 1.7 | 101.7 | 1.2 | |||
19 | A=4.119C+6.583 | 5-500 | 0.9999 | 84 | 279 | 95.4 | 2.3 | 92.6 | 2.4 | 90.4 | 1.5 | |||
20 | A=15.97C-5.058 | 5-500 | 0.9999 | 50 | 165 | 101.6 | 3.5 | 96.5 | 1.0 | 93.3 | 0.8 | |||
21 | A=9.363C+7.574 | 5-500 | 0.9999 | 25 | 84 | 102.1 | 4.0 | 97.4 | 1.4 | 95.7 | 1.1 | |||
22 | A=15.52C+13.09 | 5-500 | 0.9999 | 25 | 83 | 104.3 | 1.9 | 98.0 | 1.2 | 96.1 | 0.5 | |||
23 | A=13.42C+18.91 | 5-500 | 0.9999 | 25 | 82 | 93.5 | 1.1 | 88.9 | 3.2 | 101.8 | 0.2 | |||
24 | A=29.03C+33.56 | 5-500 | 0.9999 | 10 | 34 | 96.3 | 2.1 | 104.2 | 1.0 | 105.9 | 0.6 | |||
25 | A=13.36C+21.38 | 5-500 | 0.9999 | 25 | 84 | 96.4 | 3.5 | 95.8 | 1.4 | 93.8 | 1.2 | |||
26 | A=27.47C+32.53 | 5-250 | 0.9999 | 5 | 17 | 97.6 | 1.0 | 102.3 | 0.4 | 99.5 | 0.9 | |||
27 | A=27.26C+36.18 | 5-500 | 0.9999 | 10 | 33 | 96.3 | 0.3 | 93.0 | 2.8 | 89.9 | 2.2 | |||
28 | A=13.43C+11.58 | 5-500 | 0.9999 | 25 | 83 | 95.6 | 0.4 | 98.2 | 0.8 | 96.1 | 1.0 | |||
29 | A=15.09C+16.83 | 5-500 | 0.9999 | 50 | 165 | 99.0 | 1.9 | 99.7 | 0.9 | 93.3 | 0.5 | |||
30 | A=7.479C+10.23 | 5-500 | 0.9999 | 50 | 166 | 94.5 | 1.6 | 95.9 | 1.8 | 101.2 | 0.7 | |||
31 | A=8.930C+11.22 | 5-500 | 0.9999 | 50 | 166 | 100.2 | 1.8 | 103.2 | 1.9 | 106.2 | 1.0 | |||
32 | A=13.91C+18.68 | 5-500 | 0.9999 | 50 | 165 | 92.6 | 0.4 | 92.5 | 0.3 | 96.5 | 0.5 | |||
33 | A=25.45C+40.23 | 5-500 | 0.9999 | 10 | 34 | 95.0 | 0.2 | 97.1 | 0.9 | 100.9 | 0.3 | |||
34 | A=7.039C+4.692 | 5-500 | 0.9999 | 25 | 84 | 94.9 | 1.1 | 100.0 | 0.7 | 99.5 | 0.6 | |||
35 | A=5.679C+6.342 | 5-500 | 0.9999 | 25 | 83 | 90.4 | 0.9 | 91.7 | 1.1 | 92.9 | 1.4 | |||
36 | A=6.771C+7.516 | 5-500 | 0.9999 | 10 | 34 | 96.0 | 0.8 | 97.8 | 1.0 | 102.5 | 2.4 | |||
37 | A=2.318C+0.4190 | 5-500 | 0.9999 | 25 | 82 | 91.5 | 0.8 | 92.4 | 1.7 | 94.9 | 1.1 | |||
38 | A=6.514C+8.196 | 5-500 | 0.9999 | 5 | 17 | 90.0 | 0.5 | 91.0 | 1.0 | 94.9 | 2.0 | |||
39 | A=23.44C+43.40 | 5-250 | 0.9998 | 5 | 16 | 89.8 | 3.2 | 90.8 | 2.1 | 94.0 | 1.8 | |||
40 | A=7.160C+1.060 | 5-500 | 0.9999 | 5 | 17 | 81.4 | 1.8 | 87.4 | 2.2 | 88.8 | 2.1 |
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